Antimicrobial coatings based on amine-terminated graphene oxide and Nafion with remarkable thermal resistance.

We present a novel type of layer-by-layer (LbL) waterborne coating based on Nafion and amine-terminated graphene oxide (GO-NH2) that inhibits the growth of Escherichia coli and Staphylococcus aureus by more than 99% and this performance is not compromised upon extensive thermal annealing at 200 °C. Quartz crystal microbalance (QCM) sensorgrams allow the real time monitoring of the build-up of the LbL assemblies, a process that relies on the strong electrostatic interactions between Nafion (pH = 2.7, ζ = -54.8 mV) and GO-NH2 (pH = 2, ζ = 26.7 mV). Atomic force microscopy (AFM), contact angle and zeta potential measurements were used to characterise the multilayer assemblies. We demonstrate here that Nafion/GO-NH2 advanced coatings can offer drug-free and long-lasting solutions to microbial colonization and can withstand dry heat sterilization, without any decline in their performance.

Resculpting carbon dots via electrochemical etching.

Substantial efforts are directed into exploring the structure-properties relationships of photoluminescent Carbon dots (C-dots). This study unravels a resculpting mechanism in C-dots that is triggered by electrochemical etching and proceeds via extensive surface oxidation and carbon-carbon breakage. The process results in the gradual shrinkage of the nanoparticles and can enhance the quantum yield by more than half order of magnitude compared to the untreated analogues.

Towards Red Emissive Systems Based on Carbon Dots.

Carbon dots (C-dots) represent an emerging class of nontoxic nanoemitters that show excitation wavelength-dependent photoluminescence (PL) with high quantum yield (QY) and minimal photobleaching. The vast majority of studies focus on C-dots that exhibit the strongest PL emissions in the blue/green region of the spectrum, while longer wavelength emissions are ideal for applications such as bioimaging, photothermal and photodynamic therapy and light-emitting diodes. Effective strategies to modulate the PL emission of C-dot-based systems towards the red end of the spectrum rely on extensive conjugation of sp2 domains, heteroatom doping, solvatochromism, surface functionalization and passivation. Those approaches are systematically presented in this review, while emphasis is given on important applications of red-emissive suspensions, nanopowders and polymer nanocomposites.