Antifouling Property of Cu2O-Free Self-Polishing Antifouling Coatings Based on Amide Derivatives Inspired by Capsaicin.

The evidence from many studies shows that antifoulants (Cu2O) and organic antifouling agents with broad-spectrum characteristics in antifouling coatings cause varying degrees of damage to the environment. Therefore, this study prepared Cu2O-free self-polishing antifouling coatings based on amide derivatives inspired by capsaicin (ADIC-CSAC) with green and environmentally friendly characteristics. First, the structure of ADIC and the composition of ADIC-CSAC were characterized by IR, 1H NMR, 13C NMR, HRMS, and EDX. Moreover, antibacterial, anti-algal, static raft tests and changes in the mass loss, roughness, contact angle, and surface energy were used to evaluate the antifouling and self-polishing properties of ADIC-CSAC. The test results showed that ADIC and ADIC-CSAC were successfully prepared and ADIC-CSAC possessed good antifouling and self-polishing properties. ADIC-CSAC exhibited antibacterial and anti-algal rates of over 88 and 72%, respectively, and was found to have satisfactory antifouling properties over 9 months in a real marine field. Overall, the prepared ADIC-CSAC possesses good and green antifouling and self-polishing properties, which lays a foundation for research on green antifouling coatings used for environmental protection.

Self-polishing antifouling coatings based on benzamide derivatives containing capsaicin.

In this study, N-hydroxymethylbenzamide was alkylated with various aromatic compounds to obtain five novel benzamide derivatives containing capsaicin (BDCC), and the BDCC were incorporated into coatings as auxiliary agents. The relationships between properties and structures were discussed based on experimental and theoretical results. The theoretical results showed the optimized configurations of BDCC and confirmed that the benzene ring, phenolic hydroxyl, ester and amide groups were active sites. Experimental results indicated that the antimicrobial and antifouling effects of compounds b1, b2 and b3 were better than those of chlorothalonil, their MIC and MBC values were no more than 64 and 512 µg·mL-1, and their test panels were covered only with small amounts of dirt and biofilms; they worked well as green antifouling additives. The experimental and theoretical results showed that BDCC and BDCC antifouling coatings were effective and eco-friendly.

Characterization of a New HIV-1 CRF01_AE/B Recombinant Virus Form Among Men Who Have Sex with Men in Baoding, Hebei, China.

We analyzed the near full-length genome (NFLG) of an HIV-1-positive sample(027A) with an undetermined subtype to determine the recombinant characteristics and possible source of the parental virus. 027A is a novel HIV-1 second-generation recombinant form composed of CRF01_AE and subtype B, detected from a married HIV-1-positive male subject who was infected through homosexual transmission in Baoding, Hebei province, China. The NFLG phylogenetic tree analysis suggested that the strain was close to circulation recombinant forms' (CRFs') reference sequences involved with CRF01_AE, but formed a distinct monophyletic cluster separately from them. This indicated that the strain might be a unique CRF01_AE-related recombinant from. Furthermore, the results of RIP and jpHMM further demonstrated that the NFLG sequence of the strain was composed of CRF01_AE and subtype B. The strain was two CRF01_AE fragments inserted into B backbone. Phylogenetic analysis illustrated that the CRF01_AE subregions were from the previously identified CRF01_AE cluster 4, and the B subregions were correlated with the B strains originated from Europe and America. They were all the lineages widely prevalent in men who have sex with men (MSM) population in China. In recent years, a large number of recombinant originated from CRF01_AE and B strains are constantly emerging in MSM population in China. This continual and recurrent recombination between CRF01_AE and B in high-risk group people deserves more attention and further monitoring.

Inhibiting Coking of Lubricating Oil and Thermal Insulation of Bearing Chamber Wall by TCA-2 Nitride Ceramic Coating.

High temperature around the rear bearing chamber of supersonic aero-engines often causes the coking of the lubricating oil on the shaft end cover. To figure out the problem, a method using the TCA-2 nitride ceramic coating with the thickness of several micrometers is proposed. A simulation experiment method of lubricating oil coking for high-temperature parts is developed, and the anticoking performance of the samples with the coating is studied. The results showed that the TCA-2 coating inhibits the coke of lubricating oil on the metal surface within a certain temperature range by about 40.7% under the 500 °C attributed to the decrease in the surface activity of high-temperature metal and increase in the heat resistance. The TCA-2 coating also shows good compatibility with the lubricating oil since the acid value change of lubricating oil decreases after the thermal oxidation experiment. The TCA-2 coating can effectively reduce the surface temperature of the oil side.

Camouflage versus running performance as strategies against predation in a lizard inhabiting different habitats.

Running speed and camouflage are associated with the foraging and anti-predator abilities of animals. The toad-headed lizard, Phrynocephalus versicolor, has evolved a darker dorsal color in melanistic habitats and maintained a lighter color in adjacent, non-melanistic habitats. We test the hypothesis that lizards have weaker running speed on well-matching backgrounds than on less matching backgrounds. We used lizard models to compare the predation pressure, while the running speed of dark and light lizards were compared in field tunnels using a video recording method. Our results indicated that both the dark lizards in melanistic Heishankou (HSK) and the light lizards in non-melanistic Guazhou (GZ) face lower predation pressure than potential color-background unmatched lizards. The light lizards have a potentially higher running speed than darker lizards in melanistic habitats, which implies that substrate color matching populations with benefits of camouflage might have lower anti-predation pressure, and the costs of investment in melanin production may reduce running capacity.

Experimental Investigation of Inductive Sensor Characteristic for Blade Tip Clearance Measurement at High Temperature.

Turbine tip clearance of aero-engine is important to engine performance. Proper tip clearance can reduce the gas leakage over turbine blade tips and improve the engine efficiency of turbo machinery and reduce the fuel consumption. Therefore, accurate tip clearance measurement is essential. The inductive measurement method is one of the non-contact distance measurement methods, which has the characteristics of high sensitivity, fast response speed, and strong anti-interference ability. Based on the principle of inductive sensor measuring tip clearance, the ambient temperature change may cause the material electromagnetic performance change for the conductivity and permeability varies with temperature. In order to verify the temperature effect on the sensor performance, the repeated calibration experiments were carried out to obtain the sensor repeatability error of 5.4%. Then, the sensor was calibrated in the range of 0mm-4mm clearance at temperature from 600 °C to 1000 °C and obtained the measurement error of 4.6%. Results indicate when the temperature ranged from 600 °C to 1000 °C, clearance measurement error is smaller than the sensor repeatability error so the temperature effect on the sensor characteristics can be ignored. This conclusion makes the sensor promising for monitoring the blade tip clearances at various temperature environment.

Experimental Investigation of High Temperature-Resistant Inductive Sensor for Blade Tip Clearance Measurement.

Turbine tip clearance of aero-engine is important to engine performance. Proper control of rotor tip clearance contributes to engine efficiency improvement and fuel consumption reduction. Therefore, accurate tip clearance measurement is essential. The inductive measurement method is one of the non-contact distance measurement methods, which has the characteristics of high sensitivity, fast response speed and strong anti-interference ability. Based on the principle of inductive sensor measuring tip clearance, the ambient temperature change will cause the material electromagnetic performance change for the conductivity and permeability varies with temperature. The calibration experiment was conducted to obtain the sensor resolution and sensing range. The effect of temperature on sensor parameters was extracted from high temperature experiment data. Results show the resolution of planar coil made of platinum wire can be 10 µm and the maximum sensing range can reach 5 mm. At temperature from 500 ℃ to 1100 ℃, coil inductance almost does not change with temperature while coil resistance varies exponentially with temperature, that means the coil inductance variation can reflect the tip clearance change and resistance can indicate the measuring temperature.

Mutations in COL1A1 Gene Change Dentin Nanostructure.

Although many studies have attempted to associate specific gene mutations with dentin phenotypic severity, it remains unknown how the mutations in COL1A1 gene influence the mechanical behavior of dentin collagen and matrix. Here, we reported one osteogenesis imperfecta (OI) pedigree caused by two new inserting mutations in exon 5 of COL1A1 (NM_000088.3:c.440_441insT;c.441_442insA), which resulted in the unstable expression of COL1A1 mRNA and half quantity of procollagen production. We investigated the morphological and mechanical features of proband's dentin using atomic force microscope (AFM), scanning electron microscope, and transmission electron microscope. Increased D-periodic spacing, variably enlarged collagen fibrils coating with fewer minerals were found in the mutated collagen. AFM analysis demonstrated rougher dentin surface and sparsely decreased Young's modulus in proband's dentin. We believe that our findings provide new insights into the genetic-/nano- mechanisms of dentin diseases, and may well explain OI dentin features with reduced mechanical strength and a lower crosslinked density.

Asynchronous marine-terrestrial signals of the last deglacial warming in East Asia associated with low- and high-latitude climate changes.

A high-resolution multiproxy record, including pollen, foraminifera, and alkenone paleothermometry, obtained from a single core (DG9603) from the Okinawa Trough, East China Sea (ECS), provided unambiguous evidence for asynchronous climate change between the land and ocean over the past 40 ka. On land, the deglacial stage was characterized by rapid warming, as reflected by paleovegetation, and it began ca. 15 kaBP, consistent with the timing of the last deglacial warming in Greenland. However, sea surface temperature estimates from foraminifera and alkenone paleothermometry increased around 20-19 kaBP, as in the Western Pacific Warm Pool (WPWP). Sea surface temperatures in the Okinawa Trough were influenced mainly by heat transport from the tropical western Pacific Ocean by the Kuroshio Current, but the epicontinental vegetation of the ECS was influenced by atmospheric circulation linked to the northern high-latitude climate. Asynchronous terrestrial and marine signals of the last deglacial warming in East Asia were thus clearly related to ocean currents and atmospheric circulation. We argue that (i) early warming seawater of the WPWP, driven by low-latitude insolation and trade winds, moved northward via the Kuroshio Current and triggered marine warming along the ECS around 20-19 kaBP similar to that in the WPWP, and (ii) an almost complete shutdown of the Atlantic Meridional Overturning Circulation ca. 18-15 kaBP was associated with cold Heinrich stadial-1 and delayed terrestrial warming during the last deglacial warming until ca. 15 kaBP at northern high latitudes, and hence in East Asia. Terrestrial deglacial warming therefore lagged behind marine changes by ca. 3-4 ka.