ABSTRACT
Recent advancements in polymer science and manufacturing technologies triggered new developments of porous materials used for mitigating heat losses, such as thermal insulating polymeric foams. The major bottleneck in the optimization of these products, however, remains the absence of analytical methods able to scrutinize their large design space reasonably quickly and cost-effectively. This manuscript targets the paucity of data for polymeric foams by illustrating, at a proof-of-principle level, that several well-established analytical methods including optical microscopy, pycnometry, dielectric spectroscopy, thermogravimetric analysis, and nuclear magnetic resonance can be exploited for an extensive, yet logistically efficient, characterization of these materials. The purpose of this study is thus introducing an experimental platform for the characterization of market foam products and for the development of new polymeric foams with pore sizes that are particularly relevant for industrial and residential thermal insulation. Since this work introduces several new methodologies, it may be used as a guide for both laboratory users and specialists in the field, who may further improve the herein proposed experimental concepts.