A 60 GHz Slotted Array Horn Antenna for Radar Sensing Applications in Future Global Industrial Scenarios.

This paper presents the design of a 60 GHz millimeter-wave (MMW) slot array horn antenna based on the substrate-integrated waveguide (SIW) structure. The novelty of this device resides in the achievement of a broad impedance bandwidth and high gain performance by meticulously engineering the radiation band structure and slot array. The antenna demonstrates an impressive impedance bandwidth of 14.96 GHz (24.93%), accompanied by a remarkable maximum reflection coefficient of -39.47 dB. Furthermore, the antenna boasts a gain of 10.01 dBi, showcasing its outstanding performance as a high-frequency antenna with a wide bandwidth and high gain. To validate its capabilities, we fabricated and experimentally characterized a prototype of the antenna using a probe test structure. The measurement results closely align with the simulation results, affirming the suitability of the designed antenna for radar sensing applications in future global industrial scenarios.

Design of High-Gain Antenna Arrays for Terahertz Applications.

A terahertz band (0.1-10 THz) has the characteristics of rich spectrum resources, high transmission speed, strong penetration, and clear directionality. However, the terahertz signal will suffer serious attenuation and absorption during transmission. Therefore, a terahertz antenna with high gain, high efficiency, and wide bandwidth is an indispensable key component of terahertz wireless systems and has become a research hotspot in the field of antennas. In this paper, a high-gain broadband antenna is presented for terahertz applications. The antenna is a three-layer structure, fed by a grounded coplanar waveguide (GCPW), using polytetrafluoroethylene (PTFE) material as the dielectric substrate, and the metal through-hole of the dielectric substrate forms a substrate-integrated waveguide (SIW) structure. The metal fence structure is introduced to reduce the coupling effect between the radiation patches and increase the radiation bandwidth and gain. The center frequency is 0.6366 THz, the operating bandwidth is 0.61-0.68 THz, the minimum value of the voltage standing wave ratio (VSWR) is 1.00158, and the peak gain is 13.14 dBi. In addition, the performance of the designed antenna with a different isolation structure, the length of the connection line, the height of the substrate, the radius of the through-hole, and the thickness of the patch is also studied.

An L-Slot Frequency Reconfigurable Antenna Based on MEMS Technology.

Given the shortage of spectrum resources and the demand for communication systems of diminutive size, multi-function, and adaptive characteristics, this paper proposes an L-slot frequency reconfigurable antenna based on the MEMS switch. The antenna size is 4.07 × 5.27 mm2 and is suitable for the U-band. The antenna structure consists of two RF MEMS switches, a Rogers RT5880 dielectric substrate, an L-slot patch, and a full-coverage ground. The switch is of a series contact structure and is arranged at the corner of an L-slot. By controlling the on and off state of the switch, the antenna can switch between four states of 42.36, 47.65, 53.13, and 56.72 GHz. According to the simulation results in CST STUDIO SUITE 2018, the maximum gain of the antenna is 7.90 dB, the impedance bandwidth of each state is above 1 GHz, and the direction is mainly consistent. The antenna can meet the demand for multi-frequency millimeter wave communication.

Repeated pulmonary nodules as the primary symptom of familial hemophagocytic lymphohistiocytosis in adults: a case report and review.

Pulmonary nodules are usually considered to be associated with malignant tumors and benign lesions, such as granuloma, pulmonary lymph nodes, fibrosis, and inflammatory lesions. Clinical cases of pulmonary nodules associated with hemophagocytic lymphohistiocytosis have rarely been reported. Therefore, when patients develop pulmonary nodules, the possibility of developing hemophagocytic lymphohistiocytosis is often not considered. We report the first case of familial hemophagocytic lymphohistiocytosis with recurrent pulmonary nodules as the first symptom. Our findings will hopefully provide new ideas for the diagnosis and treatment of pulmonary nodules in the future.

Design of a Ka-Band Five-Bit MEMS Delay with a Coplanar Waveguide Loaded U-Shaped Slit.

This paper designs a five-bit microelectromechanical system (MEMS) time delay consisting of a single-pole six-throw (SP6T) RF switch and a coplanar waveguide (CPW) microstrip line. The focus is on the switch upper electrode design, power divider design, transmission line corner compensation structure design, CPW loading U-shaped slit structure design, and system simulation. The switch adopts a triangular upper electrode structure to reduce the cantilever beam equivalent elastic coefficient and the closed contact area to achieve low drive voltage and high isolation. The SP6T RF MEMS switch uses a disc-type power divider to achieve consistent RF performance across the output ports. When designed by loading U-shaped slit on transmission lines and step-compensated tangents at corners, the system loss is reduced, and the delay amount is improved. In addition, the overall size of the device is 2.1 mm × 2.4 mm × 0.5 mm, simulation results show that the device has a delay amount of 0-60 ps in the frequency range of 26.5-40 GHz, the delay accuracy at the center frequency is better than 0.63 ps, the delay error in the whole frequency band is less than 22.2%, the maximum insertion loss is 3.69 dB, and the input-output return rejection is better than 21.54 dB.

Ultra-Wideband and Narrowband Switchable, Bi-Functional Metamaterial Absorber Based on Vanadium Dioxide.

A switchable ultra-wideband THz absorber based on vanadium dioxide was proposed, which consists of a lowermost gold layer, a PMI dielectric layer, and an insulating and surface vanadium dioxide layer. Based on the phase transition properties of vanadium dioxide, switching performance between ultra-broadband and narrowband can achieve a near-perfect absorption. The constructed model was simulated and analyzed using finite element analysis. Simulations show that the absorption frequency of vanadium dioxide above 90% is between 3.8 THz and 15.6 THz when the vanadium dioxide is in the metallic state. The broadband absorber has an absorption bandwidth of 11.8 THz, is insensitive to TE and TM polarization, and has universal incidence angle insensitivity. When vanadium dioxide is in the insulating state, the narrowband absorber has a Q value as high as 1111 at a frequency of 13.89 THz when the absorption is more excellent than 99%. The absorber proposed in this paper has favorable symmetry properties, excellent TE and TM wave insensitivity, overall incidence angle stability, and the advantages of its small size, ultra-widebands and narrowbands, and elevated Q values. The designed absorber has promising applications in multifunctional devices, electromagnetic cloaking, and optoelectronic switches.

Terahertz Biaxial Strain Sensor Based on Double-Upright Cross Metamaterial.

In this article, a terahertz metamaterial biaxial strain pressure sensor structure is proposed, which can address the problems of the low sensitivity, the narrow pressure measurement range, and the uniaxial-only detection of existing terahertz pressure sensors. The performance of the pressure sensor was studied and analyzed using the time-domain finite-element-difference method. By changing the substrate material and optimizing the structure of the top cell, the size of the structure that can simultaneously improve the range and sensitivity of the pressure measurements was determined. The simulation results show that the sensor has a pressure-sensing effect in the frequency range of 1.0-2.2 THz under the conditions of transverse electric (TE) and transverse magnetic (TM) polarization, and the sensitivity can reach up to 346 GHz/µm. The proposed metamaterial pressure sensor has significant applications in the remote monitoring of target structure deformation.

Investigation of charge dynamics in dinuclear cobalt phthalocyanine ammonium sulfonate (PDS) modified Ti-Fe2O3 photoanodes for photoelectrochemical water oxidation.

The kinetic competition between water oxidation/electron extraction processes and recombination behaviors is a key consideration in the development of efficient photoanodes for solar-driven water splitting. Investigating the photogenerated charge behaviors could guide the construction of high-efficiency photoanodes. In this study, the charge carrier kinetics involved in photoelectrochemical water oxidation of PDS/Ti-Fe2O3 were analyzed using surface photovoltage (SPV), transient photovoltage (TPV), short-pulse transient photocurrent (TPC) and photoelectrochemical impedance spectra (PEIS). The TPC results indicate the interfacial electric field introduced by the PDS loading increases the electron extraction and suppresses the bulk recombination, enhancing the spatial separation of photogenerated charges, which is consistent with the SPV and TPV results. Besides, the surface recombination of the back electron (BER) is also attenuated, which enhances the long-lived holes at the surface of PDS/Ti-Fe2O3 photoanode. Similarly, as obtained by PEIS fitting, the loading of PDS accelerates holes transfer at the photoanode/electrolyte interface, and increases the utilization of long-lived holes. In other word, the recombination behaviors of photogenerated charges are restrained both in the bulk and surface of the photoanode after the deposition of PDS, leading to enhanced PEC performance. These findings highlight the importance of understanding charge carrier dynamics in the design of high-efficient photoanodes.

Exploration and Validation of Potential Biomarkers and Therapeutic Targets in Ferroptosis of Asthma.

Purpose: Asthma is a chronic inflammatory airway disease involving multiple mechanisms, of which ferroptosis is a form of programmed cell death. Recent studies have shown that ferroptosis may play a crucial role in the pathogenesis of asthma, but no specific ferroptosis gene has been found in asthma, and the exact mechanism is still unclear. The present study aimed to screen ferroptosis genes associated with asthma and find therapeutic targets, in order to contribute a new clue for the diagnosis and therapy of asthma. Methods: Ferroptosis-related differentially expressed genes (FR-DEGs) in asthma were selected by the GSE41861, GSE43696 and ferroptosis datasets. Next, the FR-DEGs were subjected by GO and KEGG enrichment, and the mRNA-miRNA network was constructed. Then, GSEA and GSVA enrichment analysis and Immune infiltration analysis were performed, followed by targeted drug prediction. Finally, the expression of FR-DEGs was confirmed using GSE63142 dataset and RT-PCR assay. Results: We found 13 FR-DEGs by the GSE41861, GSE43696 and ferroptosis database. Functional enrichment analysis revealed that the 13 FR-DEGs were enriched in oxidative stress, immune response, ferroptosis, lysosome, necrosis, apoptosis etc. Moreover, our results revealed the mRNA-miRNA network of the FR-DEGs and identified candidate drugs. Also, immune infiltration revealed that ELAVL1, CREB5, CBR1 and NR1D2 are associated with the immune cells and may be potential targets in asthma. Finally, 10 FR-DEGs were validated by the GSE63142 database. It was verified that 7 FR-DEGs were differentially expressed by collecting asthma patients and healthy controls. Conclusion: This study ultimately identified 7 FR-DEGs for the diagnosis and therapy of asthma. These 7 FR-DEGs contribute to oxidative stress and immune responses. This study provides potential therapeutic targets and biomarkers for asthma patients, shedding further light on the pathogenesis of asthma as well as providing new insights into the treatment of asthma.

A Multi-Frequency Omnidirectional Antenna Based on a Ring-Shaped Structure.

A multi-frequency microstrip antenna loaded with a ring-like structure has been proposed. The radiating patch on the antenna surface consists of three split-ring resonator structures, and the ground plate consists of a bottom metal strip and three ring-shaped metals with regular cuts to form a defective ground structure. The proposed antenna works in six different frequency bands covering 1.10, 1.33, 1.63, 1.97, 2.08, and 2.69 GHz and works entirely when connected to 5G NR (FR1, 0.45-3 GHz), 4GLTE (1.6265-1.6605 GHz), Personal Communication System (1.85-1.99 GHz), Universal Mobile Telecommunications System (1.92-2.176 GHz), WiMAX (2.5-2.69 GHz), and other communications frequency bands. Moreover, such antennas also have stable omnidirectional radiation properties across different operating frequency bands. This antenna meets the needs of portable multi-frequency mobile devices and provides a theoretical approach for the development of multi-frequency antennas.

Correction: d-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts.

Correction for 'd-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts' by Hui Chen et al., Chem. Commun., 2022, 58, 7730-7740, https://doi.org/10.1039/D2CC02299K.

The Design of a Novel 2-42 GHz MEMS True-Time Delay Network for Wideband Phased Array Systems.

This article presents the design method of a compact MEMS switched-line true-time delay line (TTDL) network over a wide frequency range extending from 2 to 42 GHz using TTDL units. The TTDL units, namely the cascading radio frequency micro-electromechanical system (RF MEMS) switches and GCPW, were employed in the proposed TTDL network to improve the delay-bandwidth product (DBW) while maintaining its compact size and low delay variation (DV). For comparison, a theoretical analysis of the RF MEMS switch was performed while observing the switch performance with various top electrodes. The MEMS TTDL network has a compact size of 5 mm × 5 mm, with a maximum delay of 200 ps and a minimum of 30 ps. The maximum insertion loss of 9 states is 10 dB, and the in/out return loss is better than 20 dB across 2-42 GHz. The group delay variations are within ±2.5% for all the delay states over the operating frequency range. To the best of our knowledge, the proposed TTDL network obtains the most control bits among the TTDL networks offered to date.

Tunable Broadband-Narrowband and Dual-Broadband Terahertz Absorber Based on a Hybrid Metamaterial Vanadium Dioxide and Graphene.

We propose a functionally tunable terahertz (THz) metamaterial absorber, which has the switching performance between broadband-narrowband and dual-broadband near-perfect absorption due to the phase transition of Vanadium dioxide (VO2) and the tunable electrical property of graphene. The switching absorption properties are verified by computer simulation technology (CST) microwave study. The simulation results show that when VO2 is in the metallic phase, over 90% broadband absorption is realized in the 3.85-6.32 THz range. When the VO2 is in the insulating phase, the absorber shows quadruple narrowband absorption. By changing the Fermi level of graphene and the conductivity of VO2, the low-frequency broadband of 3.85-6.32 THz can be switched to the high-frequency broadband of 6.92-8.92 THz, and the absorber can be switched from a quadruple narrowband to a nearly singlefold narrowband. In addition, the proposed absorber is insensitive to polarization due to its symmetry and wide incident angle. The design may have potential applications in the THz range, such as switches, electromagnetic shielding, cloaking objects, filtering, sensing, and so on.

Synergistically Enabling Fast-Cycling and High-Yield Atmospheric Water Harvesting with Plasma-Treated Magnetic Flower-Like Porous Carbons.

Sorption-based atmospheric water harvesting (AWH) offers a promising solution to the water scarcity in arid regions. However, majority of the existing AWH sorbents are suffering from rather poor water productivity due to their slow water adsorption-desorption cycling capability especially when they are applied in high packing thickness. Herein, an oxygen plasma-treated magnetic flower-like porous carbon (P-MFPC) with large open surfaces, abundant surface oxygen-containing moieties, and excellent localized magnetic induction heating (LMIH) capacity is developed. These merits, together with the use of air-blowing-assisted water adsorption and LMIH-driven water desorption strategy, synergistically allow P-MFPC with 2 cm of packing thickness to complete a AWH cycling in 20 min and deliver a record 4.5 LH2O kg-1 day-1 of water productivity at 30% relative humidity. Synergistically enabling such an ultrafast AWH cycling at high sorbent packing thickness provides a promising way for the scalable high-yield AWH with compact AWH systems.

The Design and Fabrication of a MEMS Electronic Calibration Chip.

During the test of microelectromechanical system (MEMS) devices, calibration of test cables, loads and test instruments is an indispensable step. Calibration kits with high accuracy, great operability and small loss can reduce the systematic errors in the test process to the greatest extent and improve the measurement accuracy. Aiming at the issues of the conventional discrete calibration piece unit, which presents cumbersome calibration steps and large system loss, an integrated electronic calibration chip based on frequency microelectromechanical system (RF MEMS) switches is designed and fabricated. The short-open-load-through (SOLT) calibration states can be completed on a single chip, step by step, by adjusting the on-off state of the RF MEMS switches. The simulation results show that the operating frequency of the electronic calibration piece covers the range of DC~26.5 GHz, the insertion loss in through (thru) state is less than 0.2 dB, the return loss is less than 1.0 dB in short-circuit and open-circuit states, the return loss under load-circuit state is less than 20 dB and its size is only 2.748 mm × 2.2 mm × 0.5 mm. This novel calibration chip design has certain esteem for advancing calibration exactness and effectiveness.

Magnetic Stuffed Bun-Structured Metal-Organic Framework Monoliths with Noncompromised Accessible Pores and Highly Efficient Recycling Capability.

Development of industrially favorable metal-organic framework (MOF) monoliths is of paramount importance for their real-world applications. However, MOF monoliths prepared with the existing MOF shaping methods usually have seriously compromised accessible pores and suffer from inefficient and energy-intensive recycling, thereby greatly limiting their practical applications. We herein present a magnetic stuffed bun-structured MOF (mSBM) bead consisting of highly porous poly(vinyl alcohol) wraps stuffed with a binder-free powder mixture of UiO-66 and Fe3O4 nanoparticles. Such a unique structure and composition of the mSBM not only make its MOF component have a well-reserved crystal structure, surface area, and porosity and the corresponding accessible pores but also impart it with excellent localized magnetic induction heating (LMIH) capability that enables the sufficient heating and highly efficient recycling of the mSBM. These merits of mSBMs are further exemplified by assessing their atmospheric water adsorption and LMIH-driven water desorption performance. The mSBMs exhibit well-reserved atmospheric water adsorption capacities, up to 100% LMIH-driven water desorption, excellent reusability, and durability toward the practical applications. Our current work, therefore, demonstrates a new MOF shaping strategy to produce MOF monoliths with well-defined shapes, noncompromised accessible pores, and highly efficient recycling capabilities, paving a bright avenue to accelerate the practical applications of MOF monoliths.

d-sp orbital hybridization: a strategy for activity improvement of transition metal catalysts.

Orbital hybridization to regulate the electronic structures and surface chemisorption properties of transition metals has been extensively investigated for searching high-performance catalysts toward various reactions. Unlike conventional d-d hybridization, the d-sp hybridization interaction between transition metals and p-block elements could result in surprising electronic properties and catalytic activities. This feature article highlights the recent progress in the development of high-performance transition metal-based catalysts through the extraordinary d-sp hybridization strategy, particularly for energy-related electrocatalytic applications. We start by giving an introduction of fundamental concepts associated with electronic structures of transition metal catalysts, including the Sabatier principle, d-band theory, electronic descriptor, as well as the comparison of d-d hybridization and d-sp hybridization strategies. Then, we summarize the theoretical and experimental advances in d-sp hybridization catalysts, including p-block element-doped metal catalysts, intermetallic catalysts and supported metal catalysts, with emphasis on the important roles of d-sp hybridization in tuning catalytic performances. Finally, we present existing challenges and future development prospects for the rational design of advanced d-sp hybridization catalysts.

Sandwich-Structured Carbon Paper/Metal-Organic Framework Monoliths for Flexible Solar-Powered Atmospheric Water Harvesting On Demand.

Solar-powered atmospheric water harvesting (AWH) with metal-organic frameworks (MOFs) has been recognized as an attractive way to alleviate water shortage stress in rural arid areas given the naturally abundant solar energy. However, the existing solar-powered AWH technologies only allow a singular water production mode: either solar heating-driven AWH which usually results in rather poor water productivity due to the limited availability of sufficient sunlight or conductive heating-driven all-day AWH with significantly improved water productivity but requiring additional electricity provided with a photovoltaic module. This greatly limits the flexibility in managing AWH based on climate conditions, water productivity, and energy cost. Herein, a sandwich-structured MOF monolith (denoted as CACS) with dual heating capacity, localized solar heating (LSH) and electrical heating (LEH), is presented. Compared with LSH, the use of LEH leads to more rapid and uniform heating of CACS monoliths, thereby driving a significantly enhanced water desorption efficiency with faster kinetics. Using the CACS monolith as an AWH sorbent, a new type of atmospheric water harvester is developed and able to produce water in multiple working modes: LSH-, LEH-, and LSH-/LEH-driven AWH, thereby enabling flexible AWH on demand: direct use of sunlight for LSH-driven AWH during the sunlight-sufficient day and/or LEH-driven all-day AWH powered by a photovoltaic module particularly during the sunlight-absent/-insufficient time (night or cloudy day). When working at the LSH-/LEH-driven AWH mode, the resulting prototype delivers 1.4 LH2O kgMOF-1 day-1 of water productivity with 2.3 kW·h L-1H2O of energy consumption, corresponding to 5.4 times higher water productivity than the LSH-driven AWH working mode alone and 17.9% of energy saving at the cost of 22.2% of water productivity reduction compared with the LEH-driven AWH working mode alone. The current work, therefore, demonstrates a novel solar-powered AWH strategy that enables all-day water production with flexible choices on AWH working modes in terms of climate conditions, desired water productivity, and energy cost.

Design and Optimization of an S-Band MEMS Bandpass Filter Based on Aggressive Space Mapping.

Aggressive space mapping (ASM) is a common filter simulation and debugging method. It plays an important role in the field of microwave device design. This paper introduces ASM and presents the design and fabrication of a compact fifth-order microstrip interdigital filter with a center frequency of 2.5 GHz and a relative bandwidth of 10% using ASM. The filter used a double-layer silicon substrate structure and stepped impedance resonators (SIRs) and was optimized by ASM. After five iterations, the filter achieved the design specification, which greatly improves the efficiency of the filter design compared with the traditional method. It was fabricated on high-resistance silicon wafers by micro-electro-mechanical systems (MEMSs) technology, and the final size of the chip is 9.5 mm × 7.6 mm × 0.8 mm. The measurement results show that the characteristics of the filter are similar to the simulation results, which also shows the efficiency and precision of the ASM algorithm.

Embedding metal foam into metal-organic framework monoliths for triggering a highly efficient release of adsorbed atmospheric water by localized eddy current heating.

Using metal-organic frameworks (MOFs) to harvest water from the atmosphere represents an attractive way to alleviate the global water shortage stress. However, the intrinsic thermal insulating nature of MOFs makes it rather challenging to scale-up water production by utilizing industrially favorable bulky MOF monoliths due to the insufficient water desorption triggered by the existing water desorption methods. To overcome this challenge, metal foam (MF) embedded MOF monoliths (MF@MOFs) are presented. In MF@MOFs, MF not only serves as the backbone of MOF monoliths to support them with excellent mechanical robustness, but also enables the rapid generation of enormous localized eddy current heating (LECH) upon their exposure to an alternating magnetic field. Compared with the traditional heating methods, the use of LECH can effectively overcome the thermal insulating nature of MOF monoliths and realize their rapid and uniform heating, thereby triggering a complete water desorption from MF@MOFs with significantly improved desorption kinetics. The viability of the LECH-triggered water release method for practical atmospheric water harvesting is also validated through a newly designed LECH-based atmospheric water harvester. Note that this is the first exploration that uses LECH to overcome the intrinsic insulating nature of MOF monoliths.