ABSTRACT
Strategically engineering electrocatalysts with optimized interfacial electronic architectures and accelerated reaction dynamics is pivotal for augmenting hydrogen generation via alkaline water electrolysis on an industrial scale. Herein, a novel triple-interface heterostructure Ni3Se4-NiSe2-Co3O4 nanoarrays are designed anchored on Ti3C2Tx MXene (Ni3Se4-NiSe2-Co3O4/MXene) with significant work function difference (ΔΦ) as bifunctional electrocatalysts for water electrolysis. Theoretical calculations combined with experiments uncover the pivotal role of the interface-induced electric field in steering charge redistribution, which in turn modulates the adsorption and desorption kinetics of reaction intermediates. Furthermore, the synergistic interaction between Ni3Se4-NiSe2-Co3O4 and Ti3C2Tx MXene nanosheets endows the hybrids with a large electrochemical surface area, abundantly active sites, and high conductivity. Thus, Ni3Se4-NiSe2-Co3O4/MXene manifests exceptional catalytic prowess for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). In addition, the Ni3Se4-NiSe2-Co3O4/MXene electrocatalyst in the water electrolyzer delivers excellent performance and maintains commendable stability beyond 100 h of electrocatalytic operation.