A topological nodal line semi-metal with a negative Poisson's ratio in a three-dimensional carbon network with sp2 hybridization.

In carbon allotropes, a series of topological semi-metals have been predicted, but both novel electronic properties and mechanical characteristics, e.g., a negative Poisson's ratio (NPR), are rarely discovered in the same sp2 type system. Here, a new three-dimensional carbon network, named WZGN, constructed from distorted one-dimensional zigzag graphene nanoribbons is proposed. The stability of the system is fully ensured by the phonon dispersion, AIMD simulation, and binding energy calculations. Besides, it is found that the system holds both topologically protected nodal line semi-metal properties together with an NPR property. Especially, the value of the NPR can exceed -0.36 when 21% uniaxial tensile strain along the c'-direction is applied. Our findings point out that nodal line semi-metals can be compatible with intrinsic NPR properties in a wide strain range in carbon systems with sp2 hybridization, suggesting possible applications in mechanical and electronics fields.

Photo-Electro-Thermal Textiles for Scalable, High-Performance, and Salt-Resistant Solar-Driven Desalination.

Solar-driven interfacial evaporation is an emerging desalination technology that can potentially relieve the freshwater scarcity issue. To obtain high and continuous evaporation rates for all-weather, chemically engineered structural materials have been widely explored for simultaneous photothermal and electrothermal conversion. However, many previously reported fabrication processes involve poor integration and considerable energy loss. Herein, a scalable photo-electro-thermal textile is proposed to enable high efficiency, long-term salt rejection, and solar-driven desalination. Specifically, the photo-electro-thermal yarns with a core (commercial electric wire)-shell (polypyrrole-decorated Tencel) structure realize the integration of electrothermal and photothermal conversion. The wrapping eccentricity of 1.53 mm and pitch of 3 T cm-1 for the electric wire are rationally regulated to achieve a high surface temperature of over 52 °C at a 3 V DC input. As a result, exceptional and stable evaporation rates of 5.57 kg m-2 h-1 (pure water) and 4.89 kg m-2 h-1 (3.5 wt.% brine) under 1 kW m-2·radiation with a 3 V input voltage are realized. Practical application shows that the textiles can achieve high water collection of over 46 kg m-2 d-1 over the whole day of operation. The constructed photo-electro-thermal textile-based evaporator provides an effective method for commercial and scalable photo-electro-thermal conversion to achieve high-performance and salt-resistant solar-driven desalination.

Research and Application of Terahertz Response Mechanism of Few-Layer Borophene.

The terahertz stealth and shielding performance of a new type of two-dimensional material, borophene, has been studied theoretically and experimentally. Studies have shown that borophene materials have good terahertz stealth and shielding properties. First-principles calculations show that compared with single-layer borophene, few-layer borophene has good terahertz stealth and shielding performance in the range of 0.1~2.7 THz. In the range of 2~4 layers, the terahertz stealth and shielding performance of few-layer borophene increases with the increase of the number of layers. The finite element simulation calculation results also confirmed this point. Using the few-layer borophene prepared by our research group as a raw material, a PDMS composite was prepared to verify the terahertz stealth and shielding performance of the few-layer borophene. In the ultra-wide frequency range of 0.1~2.7 THz, the electromagnetic shielding effectiveness (EMI SE) of the PDMS material mixed with few-layer borophene can reach 50 dB, and the reflection loss (RL) can reach 35 dB. With the concentration of few-layer borophene increasing, the terahertz stealth and shielding effectiveness of the material is enhanced. In addition, the simultaneous mixing of few-layer borophene and few-layer graphene will make the material exhibit better terahertz stealth and shielding performance compared with mixing separately.

High-Yield Production of Few-Layer Graphene via New-fashioned Strategy Combining Resonance Ball Milling and Hydrothermal Exfoliation.

Graphene shows great potential applications in functional coating, electrodes, and ultrasensitive sensors, but high-yield and scalable preparation of few-layer graphene (FLG) by mechanical exfoliation method is still a formidable challenge. In this work, a novel two-step method for high-yield preparation of FLG is developed by combining resonance ball milling and hydrothermal treatment. During the resonance ball milling process, the utilization of magnetic Fe3O4 nanoparticles as a new "particle wedge" is beneficial to facilitate fragment and delamination of graphitic layers. In addition, further hydrothermal treatment can enhance ball milling product (BMP) exfoliation because of the shear force driven by the Brownian motion of various molecules at high temperature and high pressure. As expected, the two-step method can have high exfoliation efficiency up to 92% (≤10 layers). Moreover, the FLG nanosheet ink can easily achieve the formation of FLG coatings on the surface of various substrates, resulting in good electrical conductivity, which possesses potential applications in various fields including functional coating, energy storages, and electrochemical sensors, etc. Our work provides a new-fashioned strategy for mechanical large-scale production of graphene.

Few-Layer Borophene Prepared by Mechanical Resonance and Its Application in Terahertz Shielding.

Once two-dimensional boron-based materials were forecasted, their excellent physical and chemical properties have realized attractive application value in the field of materials science. However, borophene could not exist independently and stably in nature. Molecular beam epitaxy is the only way being used currently for the preparation of borophene, which has low yield and harsh experimental installation conditions. Here, we propose the theory that few-layer borophene supported by silver nanoparticles can exist stably and large-scale preparation of few-layer borophene can be performed by mechanical resonance first. We have revealed that the structure of the prepared borophene is α-sheet and its thickness is less than 4 nm. The oxidation rate of borophene from the experiment is about 0.19, which indicates that the few-layer borophene possesses good structure stability. We have also studied the structure stability of borophene on silver nanoparticles by first principles calculation. The calculation proves that few-layer borophene can exist stably supported with silver nanoparticles. Furthermore, the terahertz shielding and stealth performance of the few-layer borophene have been explored. The maximum terahertz shielding effectiveness value of the prepared material could reach up to 50 and 21.5 dB for the reflection loss value in the broadband range of 0.1-2.7 THz. The large-scale preparation of few-layer borophene through the mechanical method makes it possible to study the properties of borophene and achieve low-cost large-scale applications, such as the study of terahertz shielding and stealth performance in the article, which facilitates the lightweight material design for terahertz shielding and stealth.

Induction of long-lived room temperature phosphorescence of carbon dots by water in hydrogen-bonded matrices.

Phosphorescence shows great potential for application in bioimaging and ion detection because of its long-lived luminescence and high signal-to-noise ratio, but establishing phosphorescence emission in aqueous environments remains a challenge. Herein, we present a general design strategy that effectively promotes phosphorescence by utilising water molecules to construct hydrogen-bonded networks between carbon dots (CDs) and cyanuric acid (CA). Interestingly, water molecules not only cause no phosphorescence quenching but also greatly enhance the phosphorescence emission. This enhancement behaviour can be explained by the fact that the highly ordered bound water on the CA particle surface can construct robust bridge-like hydrogen-bonded networks between the CDs and CA, which not only effectively rigidifies the C=O bonds of the CDs but also greatly enhances the rigidity of the entire system. In addition, the CD-CA suspension exhibits a high phosphorescence lifetime (687 ms) and is successfully applied in ion detection based on its visible phosphorescence.

Synthesis of Water-Soluble Ag2S Quantum Dots with Fluorescence in the Second Near-Infrared Window for Turn-On Detection of Zn(II) and Cd(II).

The second near-infrared window emission (1.0-1.7 µm, NIR-II) has received extensive attention with the advantages of negligible tissue scattering, reduced autofluorescence, and less background noise. Here a novel analysis platform based on quantum dots (QDs) for highly selective detection of Zn2+ and Cd2+ with an enhanced NIR-II fluorescence is reported for the first time. We have developed a facile two-step route to synthesize the water-soluble Ag2S QDs, constituting of a green hydrothermal process and followed surface ligands exchange. Surface passivation was proposed to be the mechanism for the enhanced fluorescence. The added Zn2+ or Cd2+ could react with the surface thioglycollic acid to form Zn-thiol or Cd-thiol complex passivation shell, which restored surface defects and suppressed nonradiative recombination pathway. The detection platform exhibited a linear relationship between the ion concentrations and enhanced fluorescence and had a detection limit as low as 760 nM for Zn2+ and 546 nM for Cd2+ at pH = 7.4. Furthermore, the as-synthesized Ag2S QDs showed good robustness in real sample matrix and were demonstrated to be able to detect exogenous Zn(II) in cells. These properties suggest potential applications of detection of Zn2+ in biology and Cd2+ in environment via the NIR-II fluorescent Ag2S QDs.

Spatial distribution and pollution assessment of heavy metals in the surface sediments of the Bohai and Yellow Seas.

A total of 141 surface sediments were collected and analyzed for their geochemistry, total organic carbon, and grain size to assess the heavy metal pollution in the Bohai and Yellow Seas. The enrichment factor (EF) and geoaccumulation index (Igeo) of Cu, Pb, Zn, Cr, Cd, Ni, As, and Hg were calculated to assess anthropogenic contamination, and the results suggest that moderate Pb, Cd, and As contamination occurs in the study area. Sediment quality guidelines were applied to assess the adverse biological effects of these metals. The spatial distribution of the mean Effects Range-Median quotient for the vast majority of the study area is between 0.1 and 0.5, indicating low impact and potential negative biological effects. Multivariate analysis indicates that Cu, Pb, Zn, Cr, and Ni resulted primarily from lithogenic sources, whereas As, Cd, and Hg were mainly attributed to anthropogenic sources.