RESUMO
We report, to our best knowledge, the first observation of enhanced third upconversion Raman overtone of water in the ultraviolet region 240-380 nm by Rhodamine 6G (R6G) under intense excitation of a 532 nm laser. Its spectral peak is mostly around 288 nm. This ultraviolet spectrum has also been obtained for purified water on the Raman spectrometer LRS-3 and fluorescence spectrometer RF-5301PC, which have photomultiplier tubes. The spectral profile is approximately a triangle in most cases. Moreover, an intense and broad background is also observed to appear in the spectrum. Additionally, the conventional visible luminescence spectrum of R6G is discovered to coexist with the ultraviolet one. In comparison, the visible spectrum is much more intense.