Effective Double Electron Transport Layer Inducing Crystallization of Active Layer for Improving the Performance of Organic Solar Cells.

Interface modification plays an important role in enhancing the photoelectric conversion efficiency and stability of organic solar cells. In this work, alkali metal lithium chloride (LiCl) was introduced between indium tin oxide and polyethyleneimine ethoxylate (PEIE) to prepare a double-layer electron transport layer. Results show that the introduction of LiCl has dual functions. The first function is that LiCl can enhance conductivity, thereby facilitating charge collection. The second function is that the double-layer electron transport layer based on LiCl can induce the crystallization of active layer, thereby enhancing charge transport. Devices with LiCl/PEIE double layer achieve a high power conversion efficiency (PCE) of 3.84%, which is 21.5% higher than that of pristine devices (the PCE of pristine devices with pure PEIE interface layer is 3.16%).

Planar binary-phase lens for super-oscillatory optical hollow needles.

Optical hollow beams are suitable for materials processing, optical micromanipulation, microscopy, and optical lithography. However, conventional optical hollow beams are diffraction-limited. The generation of sub-wavelength optical hollow beams using a high numerical aperture objective lens and pupil filters has been theoretically proposed. Although sub-diffraction hollow spot has been reported, nondiffracting hollow beams of sub-diffraction transverse dimensions have not yet been experimentally demonstrated. Here, a planar lens based on binary-phase modulation is proposed to overcome these constraints. The lens has an ultra-long focal length of 300λ. An azimuthally polarized optical hollow needle is experimentally demonstrated with a super-oscillatory transverse size (less than 0.38λ/NA) of 0.34λ to 0.42λ, where λ is the working wavelength and NA is the lens numerical aperture, and a large depth of focus of 6.5λ. For a sub-diffraction transverse size of 0.34λ to 0.52λ, the nondiffracting propagation distance of the proposed optical hollow needle is greater than 10λ. Numerical simulation also reveals a good penetrability of the proposed optical hollow needle at an air-water interface, where the needle propagates through water with a doubled propagation distance and without loss of its super-oscillatory property. The proposed lens is suitable for nanofabrication, optical nanomanipulation, super-resolution imaging, and nanolithography applications.

Creating a nondiffracting beam with sub-diffraction size by a phase spatial light modulator.

Due to its unique properties of nondiffracting propagation, highly-localized intensity distribution, small beam cross-section, and self-healing, a nondiffracting beam is attractive for materials processing, microscopy, and optical research. Various methods have been investigated to generate such beams with conventional optics. However, the transverse size of those nondiffracting beams is restricted by the diffraction-limit. To overcome the diffraction limit, we use the concepts of super-oscillation and the vectorial angular spectrum method to design a phase mask mirror with a focal length of 1 m, radius of 5 mm, and numerical aperture of about 0.005 for a wavelength of 632.8 nm. The phase mask mirror was created with a phase spatial light modulator. Under the illumination of a linearly polarized Gaussian wave, a nondiffracting beam was created with sub-diffraction transverse size. The maximum transverse size of the beam is smaller than the diffraction limit of 0.5λ/NA for a propagation distance greater than 43.3 mm. A nondiffracting beam with smaller transverse size can be realized by further increasing the NA value.

Super-oscillation focusing lens based on continuous amplitude and binary phase modulation.

In this paper, we numerically demonstrate the advantage of utilizing continuous amplitude and phase modulation in super-oscillation focusing lens design. Numerical results show that compared with simple binary amplitude modulation, continuous amplitude and phase modulation can greatly improve the super-oscillation focusing performance by increasing the central lobe intensity and the ratio of its energy to the total energy, reducing the sidelobe intensity, and substantially extending the field of view. Our study also reveals the role of phase distribution in reducing the spatial frequency bandwidth of the super-oscillation optical field on the focal plane. Based on continuous amplitude and binary phase modulation, a lens was designed with double layer metal slit array for wavelength of 4.6 µm. COMSOL is used to carry out the 2D simulation. The lens focal length is 40.18λ and the focal spot FWHM is 0.308λ. Two largest sidelobes are located right next to the central lobe with intensity about 40% of the central lobe intensity. Except for the two sidelobes, other sidelobes have intensity less than 25% of the central lobe intensity, which leads to a clear field of view on the whole focal plane.