Enhanced Catalytic Hydrodeoxygenation of Activated Carbon-Supported Metal Catalysts via Rapid Plasma Surface Functionalization.

We employ a nonthermal, He/O2 atmospheric plasma as an efficient surface functionalization method of activated carbons. We show that plasma treatment rapidly increases the surface oxygen content from 4.1 to 23.4% on a polymer-based spherical activated carbon in 10 min. Plasma treatment is 3 orders of magnitude faster than acidic oxidation and introduces a diverse range of carbonyl (C═O) and carboxyl (O-C═O) functionalities that were not found with acidic oxidation. The increased oxygen functionalities reduce the particle size of a high 20 wt % loading Cu catalyst by >44% and suppress the formation of large agglomerates. Increased metal dispersion exposes additional active sites and improves the yield of hydrodeoxygenation of 5-hydroxymethyl furfural to 2,5-dimethyl furan, an essential compound for biofuel replacement, by 47%. Surface functionalization via plasma can advance catalysis synthesis while being rapid and sustainable.

Microflow chemistry and its electrification for sustainable chemical manufacturing.

Sustainability is vital in solving global societal problems. Still, it requires a holistic view by considering renewable energy and carbon sources, recycling waste streams, environmentally friendly resource extraction and handling, and green manufacturing. Flow chemistry at the microscale can enable continuous sustainable manufacturing by opening up new operating windows, precise residence time control, enhanced mixing and transport, improved yield and productivity, and inherent safety. Furthermore, integrating microfluidic systems with alternative energy sources, such as microwaves and plasmas, offers tremendous promise for electrifying and intensifying modular and distributed chemical processing. This review provides an overview of microflow chemistry, electrification, their integration toward sustainable manufacturing, and their application to biomass upgrade (a select number of other processes are also touched upon). Finally, we identify critical areas for future research, such as matching technology to the scale of the application, techno-economic analysis, and life cycle assessment.