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1.
Environ Sci Pollut Res Int ; 30(50): 108741-108756, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37751002

RESUMO

The increased occurrence and severity of natural disasters, such as landslides, have impacted the stability of phyllite rock slopes in the complex geological regions of Western China. This situation presents significant challenges for infrastructure development in the area. This study investigates the upper span bridgehead slope of Guang-Gansu expressway K550 + 031 as a case study to analyze the sliding failure mechanism of thousand rock slopes in the seismic fault zone and the supporting structure failure through field investigation and exploration. The analysis shows that the slope's rock mass is extensively fractured, primarily influenced by the Qingchuan fault zone. This geological activity leads to slope instability, worsened by seasonal rainfall. The phyllite undergoes alternating dry and wet cycles, weakening its mechanical strength, forming cracks, and accelerating slope displacement, subsidence, and cracking. This results in front slope instability, followed by gradual backward and step-by-step traction sliding deformation on both sides. The geological structure and seasonal rainfall damage the original bolt-grid beam-supporting structure. To address this issue, an anti-slide pile combined with a grid beam treatment method is proposed, and its effectiveness is verified through deep displacement monitoring. This study emphasizes the significance of integrating geological structure and seasonal rainfall impacts into infrastructure design within complex geological areas, ensuring slope and supporting structure stability.


Assuntos
Deslizamentos de Terra , China
2.
Polymers (Basel) ; 14(17)2022 Aug 30.
Artigo em Inglês | MEDLINE | ID: mdl-36080664

RESUMO

Poly (methyl methacrylate) (PMMA) bone cement is an excellent biological material for anchoring joint replacements. Tensile strength ft and fracture toughness KIC have a considerable impact on its application and service life. Considering the variability of PMMA bone cement, a three-parameter Weibull distribution method is suggested in the current study to evaluate its tensile strength and fracture toughness distribution. The coefficients of variation for tensile strength and fracture toughness were the minimum when the characteristic crack of PMMA bone cement was αch∗=8dav. Using the simple equation αch∗=8dav and fictitious crack length Δαfic=1.0dav, the mean value µ (= 43.23 MPa), minimum value ftmin (= 26.29 MPa), standard deviation σ (= 6.42 MPa) of tensile strength, and these values of fracture toughness (µ = 1.77 MPa⋅m1/2, KICmin = 1.02 MPa⋅m1/2, σ = 0.2644 MPa⋅m1/2) were determined simultaneously through experimental data from a wedge splitting test. Based on the statistical analysis, the prediction line between peak load Pmax and equivalent area Ae1Ae2 was obtained with 95% reliability. Nearly all experimental data are located within the scope of a 95% confidence interval. Furthermore, relationships were established between tensile strength, fracture toughness, and peak load Pmax. Consequently, it was revealed that peak load might be used to easily obtain PMMA bone cement fracture characteristics. Finally, the critical geometric dimension value of the PMMA bone cement sample with a linear elastic fracture was estimated.

3.
Materials (Basel) ; 15(13)2022 Jun 26.
Artigo em Inglês | MEDLINE | ID: mdl-35806620

RESUMO

Coal gangue is a kind of industrial solid waste with serious ecological and environmental implications. Producing concrete with coal gangue aggregate is one of the green sustainable development requirements. This paper reviews the properties and preparation methods of Chinese gangue aggregate, studies the influence of gangue aggregate on concrete properties and the prediction model of gangue concrete, and summarizes the influence of modified materials on gangue concrete. The studies analyzed in this review show that different treatments influence the performance of coal gangue aggregate concrete. With the increase in the replacement ratio of coal gangue aggregate in concrete, the concrete workability and mechanical performance are reduced. Furthermore, the pore structure changes lead to decreased porosity, greatly affecting the durability. Coal gangue is not recommended for producing high-grade concretes. Nevertheless, pore structure can be improved by adding mineral admixtures, fibers, and admixtures to the coal gangue concrete. Hence, the working properties, mechanical properties, and durability of the concrete can be improved effectively, ensuring that coal gangue concrete meets engineering design requirements. Adding modified materials to coal gangue concrete is a viable future development direction.

4.
Materials (Basel) ; 14(2)2021 Jan 16.
Artigo em Inglês | MEDLINE | ID: mdl-33467173

RESUMO

The Grey Relation Entropy (GRE) theory is used to analyze the sensitive pore size that affects the compressive strength of concrete. The relationship between the strength and pore structure is revised based on the sensitivity coefficient. The revised model is used to calculate the compressive strength of concrete. In order to verify the validity of the proposed model, the calculated results are compared with experimental ones, showing satisfactory agreement with a larger correlation than existing methods.

5.
Materials (Basel) ; 14(2)2021 Jan 19.
Artigo em Inglês | MEDLINE | ID: mdl-33478137

RESUMO

In this study, the high-temperature test (i.e., temperature to 1000 °C) is conducted on 600 MPa seismic steel bars, and its residual mechanical properties and constitutive relations are investigated though three cooling rates, i.e., under air, furnace, and water-cooling conditions. Results show that three cooling methods have significant effects on the apparent characteristics of 600 MPa steel bars, when the heating temperature is greater than 600 °C. In addition, the ultimate and yield strength of steel bars have been significantly affected by different cooling methods, with increasing heating temperature. However, the elastic modulus is significantly not affected by temperature. Furthermore, the elongation rate after fracture and the total elongation rate at the maximum force do not change significantly, when the heating temperature is less than 650 °C. The elongation rate, after fracture, and the total elongation rate, at the maximum force, have different changes for three cooling methods. The degeneration of the stress-strain curves occurs when the heating temperature is high. The two-fold line, three-fold line, and Ramberg-Osgood models are developed based on the stress-strain curve characteristics of steel bars after cooling. The fire resistance of 600 MPa steel bars of reinforced concrete structure is analyzed, which provides a basis for post-disaster damage assessment, repair, and reinforcement of the building structure.

6.
Mater Sci Eng C Mater Biol Appl ; 58: 730-6, 2016 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-26478365

RESUMO

A simple and green approach was developed to synthesize highly fluorescent carbon dots (CDs) using albumin as a carbon source in aqueous solution at room temperature. The CDs were characterized by excellent monodispersion, superior photostability, pH-independent emission, long fluorescence lifetime and high quantum yield (QY). The photoluminescent (PL) mechanism of CDs was explored by means of time-resolved PL decay, and the results revealed that PL originated from the emission of both defect state and intrinsic state. In addition, biological imaging with the application of CDs was carried out in human breast cancer Bcap-37 cell, which demonstrated that CDs were provided with an excellent biocompatibility, low cytotoxicity and good transmembrane ability. Besides, CDs could be considered as a potential substitute for organic dyes or semiconductor quantum dots (SQDs) in biological imaging.


Assuntos
Albuminas/química , Carbono/química , Corantes Fluorescentes/química , Imageamento Tridimensional , Medições Luminescentes/métodos , Pontos Quânticos/química , Animais , Linhagem Celular Tumoral , Sobrevivência Celular , Galinhas , Humanos , Espectroscopia Fotoeletrônica , Espectrofotometria Ultravioleta , Espectroscopia de Infravermelho com Transformada de Fourier , Difração de Raios X
7.
Colloids Surf B Biointerfaces ; 134: 235-9, 2015 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-26208294

RESUMO

A novel folate-polydiacetylene-liposome (FP-PL) with both targeted drug delivery and fluorescence tracing was prepared by thin film rehydration method. The simulated drug delivery was performed in Bcap-37 breast cancer cells and Hs578Bst normal cells in vitro. The internalization and distribution of FP-PLs in the cells were presented by fluorescence cell imaging. The results show that the FP-PLs possess low cytotoxicity, good biocompatibility and better targeting efficiency in comparison to polydiacetylene-liposomes (P-PLs).


Assuntos
Sistemas de Liberação de Medicamentos , Ácido Fólico/química , Lipossomos , Microscopia de Fluorescência/métodos , Polímeros/química , Poli-Inos/química , Linhagem Celular Tumoral , Humanos , Polímero Poliacetilênico
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