RESUMO
We report a family of organometallic rare-earth complexes with the general formula (COT)M(Cpttt) (where (COT)2- = cyclooctatetraenide, (Cpttt)- = 1,2,4-tri(tert-butyl)cyclopentadienide, M = Y(iii), Nd(iii), Dy(iii) and Er(iii)). Similarly to the prototypical Er(iii) analog featuring pentamethylcyclopentadienyl ligand (Cp*)-, (COT)Er(Cpttt) behaves as a single-ion magnet. However, the introduction of the sterically demanding (Cpttt)- imposes geometric constraints that lead to a simplified magnetic relaxation behavior compared to the (Cp*)- containing complexes. Consequently, (COT)Er(Cpttt) can be viewed as a model representative of this organometallic single-ion magnet architecture. In addition, we demonstrate that the increased steric profile associated with the (Cpttt)- ligand permits preparation, structural characterization and interrogation of magnetic properties of the early-lanthanide complex, (COT)Nd(Cpttt). Such a mononuclear derivative could not be obtained when a (Cp*)- ligand was employed, a testament to larger ionic radius of this early lanthanide ion.
RESUMO
Modern techniques for the investigation of correlated materials in the time domain combine selective excitation in the THz frequency range with selective probing of coupled structural, electronic and magnetic degrees of freedom using x-ray scattering techniques. Cryogenic sample temperatures are commonly required to prevent thermal occupation of the low energy modes and to access relevant material ground states. Here, we present a chamber optimized for high-field THz excitation and (resonant) x-ray diffraction at sample temperatures between 5 and 500 K. Directly connected to the beamline vacuum and featuring both a Beryllium window and an in-vacuum detector, the chamber covers the full (2-12.7) keV energy range of the femtosecond x-ray pulses available at the Bernina endstation of the SwissFEL free electron laser. Successful commissioning experiments made use of the energy tunability to selectively track the dynamics of the structural, magnetic and orbital order of Ca2RuO4and Tb2Ti2O7at the Ru (2.96 keV) and Tb (7.55 keV)L-edges, respectively. THz field amplitudes up to 1.12 MV cm-1peak field were demonstrated and used to excite the samples at temperatures as low as 5 K.
RESUMO
The selective amplification of DNA in the polymerase chain reaction is used to exponentially increase the signal in molecular diagnostics for nucleic acids, but there are no analogous techniques for signal enhancement in clinical tests for proteins or cells. Instead, the signal from affinity-based measurements of these biomolecules depends linearly on the probe concentration. Substituting antibody-based probes tagged for fluorescent quantification with lasing detection probes would create a new platform for biomarker quantification based on optical rather than enzymatic amplification. Here, we construct a virus laser which bridges synthetic biology and laser physics, and demonstrate virus-lasing probes for biosensing. Our virus-lasing probes display an unprecedented > 10,000 times increase in signal from only a 50% increase in probe concentration, using fluorimeter-compatible optics, and can detect biomolecules at sub-100 fmol mL-1 concentrations.
Assuntos
Técnicas Biossensoriais/métodos , DNA/análise , Lasers , Sondas de Oligonucleotídeos/química , Vírus , Anticorpos Monoclonais , Bacteriófago M13/ultraestrutura , Fenômenos Biofísicos , Técnicas Biossensoriais/instrumentação , Sondas de DNA , Elétrons , Corantes Fluorescentes , Humanos , Ligantes , Modelos Químicos , Ácidos Nucleicos , Reação em Cadeia da PolimeraseRESUMO
A planar broadband metamaterial absorber with high absorptivity working at terahertz frequencies was designed and fabricated in this work. Two nested back-to-back split-ring resonators (BSRRs) constitute a single resonator, which achieves three strong resonances, with two of them merged into a broadband peak. Cobalt silicide and parylene-C were innovatively applied as ground plane and dielectric spacer. The nested BSRR absorber experimentally realizes a bandwidth of 0.66 THz with the absorptivity above 0.8, and the highest absorptivity reaches 0.97. Taking the central frequency at 2.74 THz, the measured FWHM is 47% and the Q factor is 2.13.
Assuntos
Absorção de Radiação , Cobalto/química , Dispositivos Ópticos , Ressonância de Plasmônio de Superfície/instrumentação , Radiação Terahertz , Transdutores , Desenho de Equipamento , Análise de Falha de Equipamento , Ressonância de Plasmônio de Superfície/métodosRESUMO
We design, fabricate, and characterize dual-band terahertz (THz) metamaterial absorbers with high absorption based on structures consisting of a cobalt silicide (Co-Si) ground plane, a parylene-C dielectric spacer, and a metal top layer. By combining two periodic metal resonators that couple separately within a single unit cell, a polarization-independent absorber with two distinct absorption peaks was obtained. By varying the thickness of the dielectric layer, we obtain absorptivity of 0.76 at 0.76 THz and 0.97 at 2.30 THz, which indicates the Co-Si ground plane absorbers present good performance.