RESUMO
In the title compound, C(27)H(27)N(3)O(5)·2H(2)O, the dihydro-pyridine ring adopts a flattened boat conformation. The central pyrazole ring is essentially planar [maximum deviation of 0.003â (1)â Å] and makes dihedral angles of 50.42â (6) and 26.44â (6)° with the benzene rings. In the crystal, mol-ecules are linked via N-Hâ¯O, O-Hâ¯O, O-Hâ¯N and C-Hâ¯O hydrogen bonds into two-dimensional networks parallel to the bc plane. The crystal structure is further consolidated by weak C-Hâ¯π inter-actions.
RESUMO
In the title compound, C(20)H(21)N(3)O(4), the 1,4-dihydro-pyridine ring adopts a boat conformation. An intra-molecular C-Hâ¯O hydrogen bond generates an S(6) ring motif. The pyrazole ring makes dihedral angles of 87.81â (7) and 45.09â (7)° with the mean plane of the 1,4-dihydro-pyridine ring and the phenyl ring, respectively. In the crystal, mol-ecules are linked by N-Hâ¯N, N-Hâ¯O and C-Hâ¯O hydrogen bonds into a three-dimensional network.
RESUMO
In the title compound, C(37)H(30)N(4)O·C(4)H(8)O(2), the dihedral angle between the pyrazole and dihydro-pyrazole rings is 74.09â (10)°. In the crystal, the components are linked into centrosymmetric tetra-mers (two main mol-ecules and two solvent mol-ecules) by C-Hâ¯O hydrogen bonds. C-Hâ¯π and π-π [shortest centroid-centroid separation = 3.6546â (9)â Å] inter-actions are also observed.