1.
Chem Commun (Camb)
; 56(85): 12917-12920, 2020 Oct 27.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32974633
RESUMO
Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD+ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD+ compound, which gave the corresponding NADH analog in excellent yield.