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Environ Sci Pollut Res Int ; 25(26): 26182-26191, 2018 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-29974440

RESUMO

Palm fruit husk, a lignocellulosic material, is an agricultural solid waste. Since raw palm fruit husk does not adsorb V (V), it was subjected to surface modification with a cationic surfactant cetyl trimethyl ammonium bromide (CTAB). The surface-modified palm fruit husk showed adsorption capability for V (V). The maximum adsorption of V (V) takes place at pH 4. Adsorption equilibrium data were fitted to Langmuir, Freundlich, and Dubinin Radushkevich (D-R) isotherm models. Kinetic studies showed that the adsorption data fit second-order kinetic model better than first order. Desorption of V (V) proved that it is feasible to recover V (V) from the spent adsorbent. Effect of coexisting anions like Molybdate, sulfate, nitrate, phosphate, and thiocyanate on the adsorption of V (V) was also studied and the foreign ions compete for the adsorption sites with V (V) anionic species. Quantitative removal of V (V) was achieved from synthetic wastewater.


Assuntos
Celulose/química , Lignanas/química , Phoeniceae/química , Vanádio/isolamento & purificação , Águas Residuárias/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água , Adsorção , Agricultura , Concentração de Íons de Hidrogênio , Cinética , Molibdênio/química , Nitratos/química , Fosfatos/química , Tensoativos
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