Tough Self-Healing Materials via In Situ Growth of Zeolitic Imidazolate Framework-8 Nanocrystals in Polymers.

Construction of self-healing materials with improved mechanical performance is a great challenge. A strong and tough self-healing composite is fabricated via in situ growth of zeolitic imidazole framework-8 (ZIF-8) nanocrystals in imidazole-containing polymer networks. By adjusting the stoichiometric ratio of the zinc salt to 2-methylimidazole, composites with various mechanical performances are obtained. The existence of ZIF-8 nanocrystals via in situ growth in the polymer networks is confirmed by X-ray diffraction (XRD), transmission electron microscopy (TEM), and atomic force microscopy (AFM). The zinc-imidazole interactions between the ZIF-8 nanocrystals and the polymer are confirmed by attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. The composites can repair themselves under mild conditions owing to dynamic zinc-imidazole interactions. The self-healing efficiency of composites can reach up to 91% under the condition of 60 °C for 48 h. In contrast to the pure zinc cation crosslinking system, the composite containing ZIF-8 nanocrystals prepared via in situ growth exhibited enhanced tensile strength and toughness by 43% and 100%, respectively. This study proves that incorporating the metal-organic frameworks (MOFs) materials into a self-healing system via an in situ growth strategy is highly promising for designing self-healing materials with improved mechanical performance.

Multivariate statistical characterization of charged and uncharged domain walls in multiferroic hexagonal YMnO3 single crystal visualized by a spherical aberration-corrected STEM.

A state-of-the-art spherical aberration-corrected STEM was fully utilized to directly visualize the multiferroic domain structure in a hexagonal YMnO3 single crystal at atomic scale. With the aid of multivariate statistical analysis (MSA), we obtained unbiased and quantitative maps of ferroelectric domain structures with atomic resolution. Such a statistical image analysis of the transition region between opposite polarizations has confirmed atomically sharp transitions of ferroelectric polarization both in antiparallel (uncharged) and tail-to-tail 180° (charged) domain boundaries. Through the analysis, a correlated subatomic image shift of Mn-O layers with that of Y layers, exhibiting a double-arc shape of reversed curvatures, have been elucidated. The amount of image shift in Mn-O layers along the c-axis is statistically significant as small as 0.016 nm, roughly one-third of the evident image shift of 0.048 nm in Y layers. Interestingly, a careful analysis has shown that such a subatomic image shift in Mn-O layers vanishes at the tail-to-tail 180° domain boundaries. Furthermore, taking advantage of the annular bright field (ABF) imaging technique combined with MSA, the tilting of MnO5 bipyramids, the very core mechanism of multiferroicity of the material, is evaluated.