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1.
Chemistry ; 2020 Jan 08.
Artigo em Inglês | MEDLINE | ID: mdl-31916272

RESUMO

The design of porous materials for the recognition of multiple hydrocarbons is highly desirable for the energy-efficient separation and recognition of chemical feedstock. Herein, three new iso-structural porous discrete metal-organic cages of formula {[Pd3 (NiPr)3 PO]4 (R-AN)6 } (R-AN=anilate linkers) for the selective recognition of substituted aromatic hydrocarbons are reported. The tetrahedral cages 1, 2, and 3 containing anilate, chloranilate, and bromanilate linkers exhibited selective encapsulation of mesitylene, o-xylene, and p-xylene, respectively, over other analogous aromatic hydrocarbons. These selective encapsulations were driven by the variations in the portal diameters present at each of these cages and their interactions with the hydrocarbon guests. These observations are supported by mass spectrometry, NMR studies, and theoretical binding-energy calculations.

2.
Org Lett ; 21(6): 1617-1621, 2019 03 15.
Artigo em Inglês | MEDLINE | ID: mdl-30794417

RESUMO

An unprecedented skeletal rearrangement of 3-( tert-butylperoxy)indolin-2-one using a tin catalyst has been developed. This rearrangement is highly selective to afford a series of fluorophoric ( Z)-2-arylidene and alkylidene-2 H-benzo[ b][1,4]oxazin-3(4 H)-one derivatives in good to excellent yield. In contrast with Sn(OTf)2, the reaction of 3-( tert-butylperoxy)indolin-2-one derivatives with FeCl3 afforded the Hock fragmentation product via C-C bond cleavage.

3.
Inorg Chem ; 56(19): 11762-11767, 2017 Oct 02.
Artigo em Inglês | MEDLINE | ID: mdl-28933539

RESUMO

A novel three-dimensional coordination network 1 in a new 4,5,6-connected topology (4,5,6T115) built from linear CuII4Cl3(H2O)2 clusters and tetrahedral tetrakis(3-pyridyl)vinylsilane ligands is reported. Utilizing a similar tetrahedral ligand, tetrakis(3-pyridyl)ethylsilane, a different framework 2 having CuII2Cl(H2O)2 clusters is obtained in tcs topology. The activated sample of 1 shows an excellent and reversible uptake of I2 in solid as well as in solution phases owing to the presence of uncoordinated chloride ions and electron rich vinylic groups in it. The I2 uptake studies on the anion-exchanged samples, of bromide, iodide, and nitrate ions, show a progressive decrease in the adsorption capacity with the sample containing uncoordinated Cl- ion showing a maximum uptake of 48.5% and the one with the NO3- ions exhibiting the lowest uptake of 24.0%. These observations suggest that the halide counterions interact better with I2 in comparison with nitrate ions and the better I2 uptake in the presence of Cl- ions over the other two halides is due to its smaller size that offers a larger surface area for adsorption. Also, both these compounds were shown to be useful catalysts for the solvent-free syntheses of bis(indolyl)methanes via Friedel-Crafts alkylation reaction.

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