Recent developments on graphene and its derivatives based electrochemical sensors for determinations of food contaminants.

The sensing of food contaminants is essential to prevent their adverse health effects on the consumers. Electrochemical sensors are promising in the determination of electroactive analytes including food pollutants, biomolecules etc. Graphene nanomaterials offer many benefits as electrode material in a sensing device. To further improve the analytical performance, doped graphene or derivatives of graphene such as reduced graphene oxide and their nanocomposites were explored as electrode materials. Herein, the advancements in graphene and its derivatives-based electrochemical sensors for analysis of food pollutants were summarized. Determinations of both organic (food colourants, pesticides, drugs, etc.) and inorganic pollutants (metal cations and anions) were considered. The influencing factors including nature of electrode materials and food pollutants, pH, electroactive surface area etc., on the sensing performances of modified electrodes were highlighted. The results of pollutant detection in food samples by the graphene-based electrode have also been outlined. Lastly, conclusions and current challenges in effective real sample detection were presented.

A review on MXene and its nanocomposites for the detection of toxic inorganic gases.

In the search of the viable candidate for the sensing of pollutant gases, two-dimensional (2D) material transition metal carbides (MXenes) have attracted immense attention due to their outstanding physical and chemical properties for sensing purposes. The formation of unique 2D layered structure with high conductivity, large mechanical strength, and high adsorption properties furnish their strong interactions with gaseous molecules, which holds a promising place for developing ideal gas sensing devices. This review looks at recent achievements in diversified MXenes, with a focus gaining on in-depth understanding of MXene-based materials in room temperature inorganic gas sensors through both theoretical and experimental studies. In the first part of the review, the properties and advantages of sensing material (MXene) in comparison with other 2D materials are discussed. In the second part, the unique advantages of chemiresistive based sensors and the demerits of other detection methods are summarized in detail. This section is followed by the unique structural design of MXene bases materials for improving the sensing performance towards detection of inorganic gases. The interaction between MXene and the adsorbed gases on its surface is discussed, with a possible sensing mechanism. Finally, an overview of the current progress and opportunities for the demand of MXene is emphasized and perspectives for future improvement of the design of MXene in gas sensors are highlighted. Therefore, this review highlights the opportunities and the advancement in 2D material-based gas sensors which could provide a new avenue for rapid detection of toxic gases in the environment.

Halides and oxyhalides-based photocatalysts for abatement of organic water contaminants - An overview.

Recently, halides (silver halides, AgX; perosvkite halides, ABX3) and oxyhalides (bismuth oxyhalides, BiOX) based nanomaterials are noticeable photocatalysts in the degradation of organic water pollutants. Therefore, we review the recent reports to explore improvement strategies adopted in AgX, ABX3 and BiOX (X = Cl, Br and I)-based photocatalysts in water pollution remediation. Herein, the photocatalytic degradation performances of each type of these photocatalysts were discussed. Strategies such as tailoring the morphology, crystallographic facet exposure, surface area, band structure, and creation of surface defects to improve photocatalytic activities of pure halides and BiOCl photocatalysts are emphasized. Other strategies like metal ion and/or non-metal doping and construction of composites, adopted in these photocatalysts were also reviewed. Furthermore, the way of production of active radicals by these photocatalysts under ultraviolet/visible light source is highlighted. The deciding factors such as structure of pollutant, light sources and other parameters on the photocatalytic performances of these materials were also explored. Based on this literature survey, the need of further research on AgX, ABX3 and BiOX-based photocatalysts were suggested. This review might be beneficial for researchers who are working in halides and oxyhalides-based photocatalysis for water treatment.

A critical review on various remediation approaches for heavy metal contaminants removal from contaminated soils.

Heavy metal pollution remains a global environmental challenge that poses a significant threat to human life. Various methods have been explored to eliminate heavy metal pollutants from the environment. However, most methods are constrained by high expenses, processing duration, geological problems, and political issues. The immobilization of metals, phytoextraction, and biological methods have proven practical in treating metal contaminants from the soil. This review focuses on the general status of heavy metal contamination of soils, including the excessive heavy metal concentrations in crops. The assessment of the recent advanced technologies and future challenges were reviewed. Molecular and genetic mechanisms that allow microbes and plants to collect and tolerate heavy metals were elaborated. Tremendous efforts to remediate contaminated soils have generated several challenges, including the need for remediation methodologies, degrees of soil contamination, site conditions, widespread adoptions and various possibilities occurring at different stages of remediation are discussed in detail.

Recent progress in green and biopolymer based photocatalysts for the abatement of aquatic pollutants.

Enormous research studies on the abatement of anthropogenic aquatic pollutants including organic dyes, pesticides, cosmetics, antibiotics and inorganic species by using varieties of semiconductor photocatalysts have been reported in recent decades. Besides, many of these photocatalysts suffer in real applications owing to their high production cost and low stability. In many cases, the photocatalysts themselves are being considered as secondary pollutants. To eliminate these drawbacks, the green synthesized photocatalysts and the use of biopolymers as photocatalyst supports are considered in recent years. In this context, recent developments in green synthesized metals, metal oxides, other metal compounds, and carbon based photocatalysts in water purification are critically reviewed. Furthermore, the pivotal role of biopolymers including chitin, chitosan, cellulose, natural gum, hydroxyapatite, alginate in photocatalytic removal of aquatic pollutants is comprehensively reviewed. The presence of functional groups, electron trapping ability, biocompatibility, natural occurrence, and low production cost are the major reasons for using biopolymers in photocatalysis. Finally, the summary and conclusion are presented along with existing challenges in this research area.

Visible light driven exotic p (CuO) - n (TiO2) heterojunction for the photodegradation of 4-chlorophenol and antibacterial activity.

The treatment of industrial waste and harmful bacteria is an important topic due to the release of toxins from the industrial pollutants that damage the water resources. These harmful sources frighten the life of every organism which was later developed as the carcinogenic and mutagenic agents. Therefore, the current study focuses on the breakdown or degradation of 4-chlorophenol and the antibacterial activity against Escherichia coli (E. coli). As a well-known catalyst, pure titanium-di-oxide (TiO2) had not shown the photocatalytic activity in the visible light region. Hence, band position of TiO2 need to be shifted to bring out the absorption in the visible light region. For this purpose, the n-type TiO2 nanocrystalline material's band gap got varied by adding different ratios of p-type CuO. The result had appeared in the formation of p (CuO) - n (TiO2) junction synthesized from sol-gel followed by chemical precipitation methods. The optical band gap value was determined by Kubelka-Munk (K-M) plot through UV-Vis diffusive reflectance spectroscopy (DRS). Further, the comprehensive mechanism and the results of photocatalytic and antibacterial activities were discussed in detail. These investigations are made for tuning the TiO2 catalyst towards improving or eliminating the existing various environmental damages.