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Org Lett ; 6(19): 3289-92, 2004 Sep 16.
Artigo em Inglês | MEDLINE | ID: mdl-15355034

RESUMO

[reaction: see text] Irradiation of alpha-iodocycloalkanones bearing an allenyl side chain with a sunlamp effected atom-transfer cyclization to give cyclized products in good yield. A mechanism, involving radical atom-transfer cyclization accompanied by 1,5- and 1,4-hydrogen transfers, is proposed.

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