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Angew Chem Int Ed Engl ; 56(27): 7944-7947, 2017 06 26.
Artigo em Inglês | MEDLINE | ID: mdl-28493313

RESUMO

Low-temperature UV-photolysis of mesitylphosphiranes under highly anaerobic conditions leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X-band EPR spectrum of triplet MesP and the derived zero-field splitting parameter D=4.116 cm-1 differ significantly from those reported previously for this intermediate. New magnetic parameters of mesitylphosphinidene are discussed along with the results of DFT calculations.

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