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1.
ACS Sens ; 6(12): 4315-4324, 2021 12 24.
Artigo em Inglês | MEDLINE | ID: mdl-34842420

RESUMO

The effect of the stray field of Fe/Fe3O4 nanoparticles on the angular dependence of the microwave absorption derivative in CoFeB/Ta/CoFeB synthetic ferrimagnetic structures and CoFeB films with perpendicular anisotropy is analyzed, and its application for sensor technology is proposed. The effective field of the "platform-particles" system controlled by the magnetic dipole interaction of the CoFeB-Fe/Fe3O4 system decreased to zero in areas where the platform was magnetostatically coupled with nanoparticles. Micromagnetic modeling demonstrated the distribution of magnetization and resistance in local areas of CoFeB/Ta/CoFeB structures under the nanoparticles. The microwave absorption derivative can be used as an indicator of local magnetization switching of the giant magnetoresistance (GMR) structure under scattering fields of NPs or magnetically labeled cells. The limiting sensitivity of the detection method was 2.4 × 107 nanoparticles, which covered the spin-valve surface. We have proposed to combine the advantages of a GMR sensor with wireless technology of microwave reading of magnetoresistance for the detection of magnetically labeled cells.


Assuntos
Micro-Ondas , Nanopartículas , Magnetismo , Imãs
2.
Dalton Trans ; 49(44): 15592-15596, 2020 Nov 17.
Artigo em Inglês | MEDLINE | ID: mdl-33140783

RESUMO

Herein, we report the synthesis and magnetic properties of the Co(ii) coordination compound with the 1,1'-bis(1-((pyrid-2-ylmethylene)hydrazono)ethyl)ferrocene (L) ligand, having the general formula [CoLCl2]. The static magnetic data analysis supported by the CASSCF/NEVPT2 calculations revealed the presence of the triaxial magnetic anisotropy with Dexp = +35.2 cm-1 and large rhombicity (E/D = 0.31) in this complex (Dcalc = +34.5 cm-1, E/Dcalc = 0.30). The dynamic magnetic data confirm that the complex shows a slow field-induced (HDC = 1000 Oe) magnetic relaxation behaviour.

3.
Chemistry ; 25(64): 14583-14597, 2019 Nov 18.
Artigo em Inglês | MEDLINE | ID: mdl-31361924

RESUMO

Reactions of [Mn(H2 dapsc)Cl2 ]⋅H2 O (dapsc=2,6- diacetylpyridine bis(semicarbazone)) with K3 [Fe(CN)6 ] and (PPh4 )3 [Fe(CN)6 ] lead to the formation of the chain polymeric complex {[Mn(H2 dapsc)][Fe(CN)6 ][K(H2 O)3.5 ]}n ⋅1.5n H2 O (1) and the discrete pentanuclear complex {[Mn(H2 dapsc)]3 [Fe(CN)6 ]2 (H2 O)2 }⋅4 CH3 OH⋅3.4 H2 O (2), respectively. In the crystal structure of 1 the high-spin [MnII (H2 dapsc)]2+ cations and low-spin hexacyanoferrate(III) anions are assembled into alternating heterometallic cyano-bridged chains. The K+ ions are located between the chains and are coordinated by oxygen atoms of the H2 dapsc ligand and water molecules. The magnetic structure of 1 is built from ferrimagnetic chains, which are antiferromagnetically coupled. The complex exhibits metamagnetism and frequency-dependent ac magnetic susceptibility, indicating single-chain magnetic behavior with a Mydosh-parameter φ=0.12 and an effective energy barrier (Ueff /kB ) of 36.0 K with τ0 =2.34×10-11  s for the spin relaxation. Detailed theoretical analysis showed highly anisotropic intra-chain spin coupling between [FeIII (CN)6 ]3- and [MnII (H2 dapsc)]2+ units resulting from orbital degeneracy and unquenched orbital momentum of [FeIII (CN)6 ]3- complexes. The origin of the metamagnetic transition is discussed in terms of strong magnetic anisotropy and weak AF interchain spin coupling.

4.
J Phys Condens Matter ; 31(8): 085801, 2019 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-30628583

RESUMO

Effect of the delay between stabilization of magnetic field and recording of the reversal curve on the first order reversal curves (FORC) has been found and analyzed in K0.4[Cr(CN)6][Mn(R/S)-pn](R/S)-pnH0.6 chiral magnet. The difference between the 'delayed' and 'on time' FORC diagrams manifests the effect of magnetic relaxation on switching field of the nonlinear spin configurations presented in crystals (spin solitons, domain walls, etc). The domain walls and spin solitons with different relaxation rates contribute to reversal magnetization. The temperature dependence of magnetic anisotropy governing nonlinear spin excitations is discussed in the frames of the Callen-Callen formalism.

5.
Inorg Chem ; 56(15): 8926-8943, 2017 Aug 07.
Artigo em Inglês | MEDLINE | ID: mdl-28686422

RESUMO

Two one-dimensional cyano-bridged coordination polymers, namely, {[MnII(dapsc)][MnIII(CN)6][K(H2O)2.75(MeOH)0.5]}n·0.5n(H2O) (I) and {[MnII(dapsc)][MnIII(CN)6][K(H2O)2(MeOH)2]}n (II), based on alternating high-spin MnII(dapsc) (dapsc = 2,6-diacetylpyridine bis(semicarbazone)) complexes and low-spin orbitally degenerate hexacyanomanganate(III) complexes were synthesized and characterized structurally and magnetically. Static and dynamic magnetic measurements reveal a single-chain magnet (SCM) behavior of I with an energy barrier of Ueff ≈ 40 K. Magnetic properties of I are analyzed in detail in terms of a microscopic theory. It is shown that compound I refers to a peculiar case of SCM that does not fall into the usual Ising and Heisenberg limits due to unconventional character of the MnIII-CN-MnII spin coupling resulting from a nonmagnetic singlet ground state of orbitally degenerate complexes [MnIII(CN)6]3-. The prospects of [MnIII(CN)6]3- complex as magnetically anisotropic molecular building block for engineering molecular magnets are critically analyzed.

6.
Dalton Trans ; 46(23): 7540-7548, 2017 Jun 13.
Artigo em Inglês | MEDLINE | ID: mdl-28573307

RESUMO

We report a combined experimental characterization and theoretical modeling of the hexa-coordinated high-spin Co(ii) complex cis-[Co(hfac)2(H2O)2] (I). The magnetic static field (DC) data and EPR spectra (measurements were carried out on the powder samples of diluted samples cis-[Co0.02Zn0.98 (hfac)2(H2O)2]) were analyzed with the aid of the parametric Griffith Hamiltonian for the high-spin Co(ii) supported by the ab initio calculations of the crystal field (CF) parameters, g-factors and superexchange parameters between H-bonded Co(ii) ions in the neighboring molecules in a 1D network. This analysis suggests the presence of the easy axis of magnetic anisotropy and also shows the existence of a significant rhombic component. The detected frequency dependent (AC) susceptibility signal shows that complex I exhibits slow paramagnetic relaxation in the applied DC field belonging thus to the class of non-uniaxial field induced single ion magnets with a negative axial component of anisotropy. It is demonstrated that the main contributions to the relaxation come from the direct one-phonon process dominating at low temperatures, while the contribution of the two-phonon Raman process becomes important with increasing temperature.

7.
Inorg Chem ; 55(19): 9696-9706, 2016 Oct 03.
Artigo em Inglês | MEDLINE | ID: mdl-27632142

RESUMO

In this article we report the synthesis and structure of the new Co(II) complex Et4N[CoII(hfac)3] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis of the magnetic characteristics based on the complementary experimental techniques such as static and dynamic magnetic measurements, electron paramagnetic resonance spectroscopy in conjunction with the theoretical modeling (parametric Hamiltonian and ab initio calculations) demonstrates that the SIM properties of I arise from the nonuniaxial magnetic anisotropy with strong positive axial and significant rhombic contributions.

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