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Macromol Rapid Commun ; 41(22): e2000430, 2020 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-32989818


Conjugated polymers represent a promising family of semiconductor materials for thin-film organic solar cells (OSCs). An efficient approach to improve the photovoltaic performance of conjugated polymers is engineering the side chains attached to the polymer backbone. This work reports the impact of different alkyl substituents on the optoelectronic properties, charge carrier mobilities, thin film morphology, and photovoltaic performance of novel (X-DADAD)n conjugated polymers incorporating benzo[1,2-b:4,5-b']dithiophene moieties. It has been shown that loading conjugated polymers with appropriate alkyl side chains results in a spectacular performance improvement from 6.8% to 9% in OCSs using a model fullerene acceptor [6,6]-phenyl-C71 -butyric acid methyl ester. The obtained results feature side-chain engineering as a facile and efficient strategy for designing high-performance conjugated polymers for organic photovoltaics.

Fulerenos , Energia Solar , Estrutura Molecular , Polímeros
Nanoscale Res Lett ; 7(1): 206, 2012 Apr 03.
Artigo em Inglês | MEDLINE | ID: mdl-22471942


We have investigated the electroluminescence spectra of the electroluminescent devices based on the new zinc complexes of amino-substituted benzothiazoles and quinolines containing the C-N-M-N chains in their chelate cycles. The spectra exhibit strong exciplex bands in the green to yellow region 540 to 590 nm due to interaction of the excited states of zinc complexes and triaryl molecules of the hole-transporting layer. For some devices, the intrinsic luminescence band of 460 nm in the blue region is also observed along with the exciplex band giving rise to an almost white color of the device emission. The exciplex band can be eliminated if the material of the hole-transporting layer is not a triarylamine derivative. We have also found the exciplex emission in the photoluminescence spectra of the films containing blends of zinc complex and triphenylamine material.