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Inorg Chem ; 43(26): 8230-2, 2004 Dec 27.
Artigo em Inglês | MEDLINE | ID: mdl-15606165

RESUMO

We report on helical coordination networks that were prepared using a hexanuclear manganese metallamacrocycle as a helical tecton. We were able to prepare the three-dimensional helical coordination networks using a hexanuclear manganese metallamacrocycle, [Mn(6)(lshz)(6)], as a helical tecton, where N-lauroyl salicylhydrazide (H(3)lshz) was used as the primary building unit to generate the helical tecton as a secondary building unit. While the 4(1)/4(3) screw symmetry-linked helical coordination network was obtained when the primary building units had an N-acetyl group, both the 3(1)/3(2) screw symmetry-linked and the 4(1)/4(3) screw symmetry-linked helical coordination networks were obtained simultaneously in the same batch when the primary building unit had a long alkyl N-lauroyl group at the N-acetyl site.

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