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Org Biomol Chem ; 17(20): 4975-4978, 2019 May 28.
Artigo em Inglês | MEDLINE | ID: mdl-31050343


Despite progress in the unidirectional complexation of cyclodextrins and calixarenes with nonsymmetric guests, unidirectional complexation using pillararenes as hosts remains scarcely explored. In this report, we describe the formation of unidirectional [2]pseudorotaxane-like complexes which were realized using n-alkyl alcohol guests and pillar[4]arene[1]benzoquinoneoxime made from pillar[4]arene[1]quinone in a selective monofunctionalizing manner.

J Org Chem ; 80(16): 7994-8000, 2015 Aug 21.
Artigo em Inglês | MEDLINE | ID: mdl-26219027


A novel tricylic host molecule 1 that consists of two pillar[5]arene units and a crown ether ring was found to selectively bind two kinds of guest molecules with different shapes, sizes, and electronic constitutions, namely 1,4-dicyanobutane G1 and paraquat G2, with its two macrocyclic subunits, to form a four-component complex 2G1⊂1⊃G2. An (1)H NMR study of stepwise bindings of G1 and G2 to host 1 in CDCl3/DMSO-d6 revealed that the strength of the association between complex 2G1⊂1 and guest G2 was only one-fourth of that between free 1 and G2, demonstrating a negative heterotropic cooperativity of G1 in the binding of G2 to host 1.

Éteres de Coroa/química , Compostos Macrocíclicos/síntese química , Compostos de Amônio Quaternário/química , Sítios de Ligação , Cristalografia por Raios X , Compostos Macrocíclicos/química , Modelos Moleculares , Conformação Molecular