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1.
Opt Lett ; 46(22): 5663-5666, 2021 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-34780431

##### RESUMO

The reflection spectra of conventional fiber Bragg gratings (FBGs) with uniform index modulation profiles typically have strong sidelobes, which hamper the performance of FBG-based optical filters, fiber lasers, and sensors. Here, we propose and demonstrate a femtosecond laser line-by-line (LbL) scanning technique for fabricating apodized FBGs with suppressed sidelobes. This approach can flexibly achieve various apodized modulation profiles via precise control over the length and/or transverse position of each laser-inscribed index modification track. We theoretically and experimentally studied the influences of the apodization function on the side-mode suppression ratio (SMSR) in the fabricated apodized FBG, and the results show that a maximum SMSR of 20.6 dB was achieved in a Gaussian-apodized FBG. Subsequently, we used this method to fabricate various apodized FBGs, and the SMSRs in these FBGs were reduced effectively. Specifically, a dense-wavelength-division-multiplexed Gaussian-apodized FBG array with a wavelength interval of 1.50 nm was successfully fabricated, and the SMSR in such an array is 14 dB. Moreover, a Gaussian-apodized phase-shifted FBG and chirped FBG were also demonstrated with a high SMSR of 14 and 16 dB, respectively. Therefore, such an apodization method based on a modified femtosecond laser LbL scanning technique is an effective and flexible way to fabricate various FBGs with high SMSRs, which is promising to improve the performance of optical filters, fiber lasers, and sensors.

2.
Opt Express ; 29(20): 32615-32626, 2021 Sep 27.
Artigo em Inglês | MEDLINE | ID: mdl-34615327

##### RESUMO

Ultra-weak fiber Bragg grating (UWFBG) arrays are key elements for constructing large-scale quasi-distributed sensing networks for structural health monitoring. Conventional methods for creating UWFBG arrays are based on in-line UV exposure during fiber drawing. However, the UV-induced UWFBG arrays cannot withstand a high temperature above 450 °C. Here, we report for the first time, to the best of our knowledge, a new method for fabricating high-temperature-resistant UWFBG arrays by using a femtosecond laser point-by-point (PbP) technology. UWFBGs with a low peak reflectivity of â¼ - 45 dB (corresponding to â¼ 0.0032%) were successfully fabricated in a conventional single-mode fiber (SMF) by femtosecond laser PbP inscription through fiber coating. Moreover, the influences of grating length, laser pulse energy, and grating order on the UWFBGs were studied, and a grating length of 1 mm, a pulse energy of 29.2 nJ, and a grating order of 120 were used for fabricating the UWFBGs. And then, a long-term high-temperature annealing was carried out, and the results show that the UWFBGs can withstand a high temperature of 1000 °C and have an excellent thermal repeatability with a sensitivity of 18.2 pm/°C at 1000 °C. A UWFBG array consisting of 200 identical UWFBGs was successfully fabricated along a 2 m-long conventional SMF with an interval of 10 mm, and interrogated with an optical frequency domain reflectometer (OFDR). Distributed high-temperature sensing up to 1000 °C was demonstrated by using the fabricated UWFBG array and OFDR demodulation. As such, the proposed femtosecond laser-inscribed UWFBG array is promising for distributed high-temperature sensing in hash environments, such as aerospace vehicles, nuclear plants, and smelting furnaces.

3.
Inorg Chem ; 60(19): 14872-14879, 2021 Oct 04.
Artigo em Inglês | MEDLINE | ID: mdl-34533941

##### RESUMO

A novel organodiphosphonate-based telluromolybdate cluster, (NH4)6Na3H13[TeMo10O37(CoMo2O6L)4]·11H2O [1; L = (O3P)2C(O)(CH2)3NH2], has been successfully synthesized by a simple one-pot aqueous reaction. Intriguingly, the [TeMo10O37]10- subunit with tetrahedral geometry of TeO4 is observed in the organophosphonate-functionalized polyoxometalates for the first time. Compound 1 was prepared in a buffer solution (pH = 5.5) with alendronic acid (Ale) and (NH4)6Mo7O24·4H2O as raw materials. The polyanion [TeMo10O37(CoMo2O6L)4]22- was constructed from four {Mo2O6L} subunits encapsulating an interesting Te-Mo heterometal subunit [TeMo10O37]10- through four CoO6 octahedra and has been fully characterized by routine techniques. In addition, compound 1, as a heterogeneous catalyst, shows good conversion (92%) and high selectivity (99%) for Knoevenagel condensation reaction.

4.
Opt Lett ; 46(11): 2742-2745, 2021 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-34061102

##### RESUMO

Sapphire fiber Bragg gratings (SFBGs) inscribed by using femtosecond laser point-by-point (PbP) technology typically have an extremely low reflectivity due to the limited cross-sectional area of refractive index modulations (RIMs) created in sapphire fiber. Hence, we propose and experimentally demonstrate a filamentation process for fabricating PbP SFBGs. This approach provides an efficient method for producing SFBGs at various Bragg wavelengths with a higher reflectivity, since the filament tracks could enlarge the cross-sectional area of RIMs. The influences of the pulse energy and the focal depth on the generation and morphology of the filament tracks were studied, and after optimizing these parameters, high-quality filament tracks with a length of 90 µm and a width of 1.4 µm were produced into sapphire fiber with a diameter of 100 µm. These filament tracks were precisely assembled in sapphire fiber, generating an SFBG with a reflectivity of 2.3%. The total fabrication time for this SFBG only requires ${\sim}{1.1}\;{\rm s}$. Subsequently, a wavelength-division-multiplexed (WDM) SFBG array consisting of five SFBGs was efficiently constructed. Moreover, the high-temperature response of the SFBG array was investigated and the experimental results showed that the SFBG array can withstand a high temperature of 1600°C. Such a WDM SFBG array could serve as quasi-distributed high-temperature sensor which will be promising in many areas, i.e., metallurgical, chemical, and aviation industries.

5.
Opt Express ; 29(12): 17700-17709, 2021 Jun 07.
Artigo em Inglês | MEDLINE | ID: mdl-34154046

##### RESUMO

6.
Inorg Chem ; 60(11): 7753-7761, 2021 Jun 07.
Artigo em Inglês | MEDLINE | ID: mdl-34019402

##### RESUMO

Developing new catalysts for highly efficient and selective oxidation of saturated C-H bonds is significant due to their thermodynamic strength. Via incorporation of PW12O403-, pyridine-2,5-dicarboxylic acids (pydc), and Fe(III) ions into one framework, a new polyoxometalate-based metal-organic framework, [HFe4O2(H2O)4(pydc)3PW12O40]·10.5H2O (FeW-PYDC), was successfully prepared by a hydrothermal method. Interestingly, FeW-PYDC features a three-dimensional porous structure with {Fe4O2} interconnecting with PW12O403- units. FeW-PYDC displayed excellent performance in the selective oxidation of C-H bonds of alkylbenzenes with high conversion (95.7%) and selectivity (96.6%). As an effective heterogeneous catalyst, FeW-PYDC demonstrates good reusability and structural stability.

7.
J Genet Genomics ; 48(1): 63-74, 2021 01 20.
Artigo em Inglês | MEDLINE | ID: mdl-33832859

##### RESUMO

Cyclin-dependent kinase 1 (CDK1) plays an essential role in cell cycle regulation. However, as mouse Cdk1 embryos die early, the role of CDK1 in regulating the cell cycle and embryo development remains unclear. Here, we showed that zebrafish cdk1-/- embryos exhibit severe microphthalmia accompanied by multiple defects in S phase entry, M phase progression, and cell differentiation but not in interkinetic nuclear migration. We identified Top2a as a potential downstream target and cyclin A2 and cyclin B1 as partners of Cdk1 in cell cycle regulation via an in silico analysis. While depletion of either cyclin A2 or Top2a led to the decreased S phase entry in zebrafish retinal cells, the depletion of cyclin B1 led to M phase arrest. Moreover, phosphorylation of Top2a at serine 1213 (S1213) was nearly abolished in both cdk1 and ccna2 mutants, but not in ccnb1 mutants. Furthermore, overexpression of TOP2AS1213D, the phosphomimetic form of human TOP2A, rescued S phase entry and alleviated the microphthalmia defects in both cdk1-/- and ccna2-/- embryos. Taken together, our data suggest that Cdk1 interacts with cyclin A2 to regulate S phase entry partially through Top2a phosphorylation and interacts with cyclin B1 to regulate M phase progression.

8.
Inorg Chem ; 60(7): 4792-4799, 2021 Apr 05.
Artigo em Inglês | MEDLINE | ID: mdl-33715352

##### RESUMO

A copper-containing polyoxometalate-based metal-organic framework (POMOF), CuI12Cl2(trz)8[HPW12O40] (HENU-7, HENU = Henan University; trz = 1,2,4-triazole), has been successfully synthesized and well-characterized. In addition, the excellent catalytic ability of HENU-7 has been proved by the selective oxidation of diphenylmethane. Under the optimal conditions, the diphenylmethane conversion obtained over HENU-7 is 96%, while the selectivity to benzophenone is 99%, which outperforms most noble-metal-free POM-based catalysts. Moreover, HENU-7 is stable to reuse for five runs without an obvious loss in activity and also can catalyze the oxidation of different benzylic C-H with satisfactory conversions and selectivities, which implied the significant catalytic activity and recyclability.

9.
Micromachines (Basel) ; 12(3)2021 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-33668915

##### RESUMO

Over decades, fiber-optic temperature sensors based on conventional single-mode fibers (SMF) have been demonstrated with either high linearity and stability in a limited temperature region or poor linearity and thermal hysteresis in a high-temperature measurement range. For high-temperature measurements, isothermal annealing is typically necessary for the fiber-optic sensors, aiming at releasing the residual stress, eliminating the thermal hysteresis and, thus, improving the high-temperature measurement linearity and stability. In this article, an annealing-free fiber-optic high-temperature (1100 °C) sensor based on a diaphragm-free hollow-core fiber (HCF) Fabry-Perot interferometer (FPI) is proposed and experimentally demonstrated. The proposed sensor exhibits an excellent thermal stability and linearity (R2 > 0.99 in a 100-1100 °C range) without the need for high-temperature annealing. The proposed sensor is extremely simple in preparation, and the annealing-free property can reduce the cost of sensor production significantly, which is promising in mass production and industry applications.

10.
Sensors (Basel) ; 20(15)2020 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-32752307

##### RESUMO

A high-energy nanosecond-pulsed ultraviolet (UV) laser Talbot interferometer for high-efficiency, mass production of fiber Bragg grating (FBG) array was experimentally demonstrated. High-quality FBG arrays were successfully inscribed in both H2-free and H2-loaded standard single-mode fibers (SMFs) with high inscription efficiency and excellent reproducibility. Compared with the femtosecond pulse that had a coherent length of several tens of micrometers, a longer coherent length (~10 mm) of the employed laser rendered a wider FBG wavelength versatility over 700 nm band (1200-1900 nm) without the need for optical path difference (OPD) compensation. Dense FBG array with center wavelength separation of ~0.4 nm was achieved and more than 1750 FBGs with separated center wavelength could be inscribed in a single H2-free or H2-loaded SMF in theory, which is promising for mass production of FBG arrays in industry. Moreover, precise focusing of laser beam was superfluous for the proposed system due to the high energy density of pulse. The proposed FBG inscription system was promising for industrialization production of dense FBG arrays.

11.
Inorg Chem ; 59(15): 10665-10672, 2020 Aug 03.
Artigo em Inglês | MEDLINE | ID: mdl-32662637

##### RESUMO

A novel crown-shaped 36-molybdate cluster with organophosphonate-functionalized polyoxomolybdates, (NH4)17Na7H12[Co(H2O)TeMo6O21{N(CH2PO3)3}]6·42H2O, has been successfully synthesized and well-characterized. It owns the highest nuclearity in the family of organophosphonate-based polyoxometalates reported so far. Furthermore, for the first time in the field, we illustrated that polyoxomolybdate could work as an effective heterogeneous catalyst for the Knoevenagel condensation reaction with high TOF (7714 h-1) and good recyclability. Impressively, the catalytic performance of 1 was also tested successfully in a large scale (â¼10 g) reaction, where 89% of reaction yield and 3216 of TON were afforded.

12.
Chemistry ; 26(65): 14896-14902, 2020 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-32543759

##### RESUMO

The crown-shaped 36-molybdate cluster organophosphonate-functionalized polyoxomolybdates with the highest nuclearity in organophosphonate-based polyoxometalate chemistry, (NH4 )19 Na7 H10 [Cu(H2 O)TeMo6 O21 {N(CH2 PO3 )3 }]6 â31 H2 O, has been reported for the first time. The synthesized 36-molybdate cluster was characterized by routine techniques and tested as a heterogeneous catalyst for selective oxidation of sulfides with impressive catalytic and selective performances after heat treatment. High efficiency (TON=15333) was achieved in the selective oxidation of sulfides to sulfoxides, caused by the synergic effect between copper and polyoxomolybdates and the generation of the cuprous species during the heat treatment.

13.
Development ; 147(12)2020 06 19.
Artigo em Inglês | MEDLINE | ID: mdl-32467236

##### RESUMO

The zebrafish retina grows for a lifetime. Whether embryonic and postembryonic retinogenesis conform to the same developmental program is an outstanding question that remains under debate. Using single-cell RNA sequencing of â¼20,000 cells of the developing zebrafish retina at four different stages, we identified seven distinct developmental states. Each state explicitly expresses a gene set. Disruption of individual state-specific marker genes results in various defects ranging from small eyes to the loss of distinct retinal cell types. Using a similar approach, we further characterized the developmental states of postembryonic retinal stem cells (RSCs) and their progeny in the ciliary marginal zone. Expression pattern analysis of state-specific marker genes showed that the developmental states of postembryonic RSCs largely recapitulated those of their embryonic counterparts, except for some differences in rod photoreceptor genesis. Thus, our findings reveal the unifying developmental program used by the embryonic and postembryonic retinogenesis in zebrafish.

##### Assuntos
Embrião não Mamífero/metabolismo , Neurogênese/genética , Retina/metabolismo , Peixe-Zebra/metabolismo , Animais , Animais Geneticamente Modificados/crescimento & desenvolvimento , Animais Geneticamente Modificados/metabolismo , Proteínas de Ligação a DNA/deficiência , Proteínas de Ligação a DNA/genética , Proteínas de Ligação a DNA/metabolismo , Desenvolvimento Embrionário , Proteínas de Ligação a Ácido Graxo/deficiência , Proteínas de Ligação a Ácido Graxo/genética , Proteínas de Ligação a Ácido Graxo/metabolismo , Regulação da Expressão Gênica no Desenvolvimento , Retina/citologia , Retina/crescimento & desenvolvimento , Análise de Sequência de RNA , Análise de Célula Única , Células-Tronco/citologia , Células-Tronco/metabolismo , Fatores de Transcrição/deficiência , Fatores de Transcrição/genética , Fatores de Transcrição/metabolismo , Peixe-Zebra/crescimento & desenvolvimento , Proteínas de Peixe-Zebra/deficiência , Proteínas de Peixe-Zebra/genética , Proteínas de Peixe-Zebra/metabolismo
14.
Opt Express ; 28(10): 14850-14858, 2020 May 11.
Artigo em Inglês | MEDLINE | ID: mdl-32403519

##### RESUMO

A new optical fiber bend sensor is proposed and demonstrated based on a sandwich structure created by splicing a segment of twin core fiber (TCF) between two segments of single mode fibers (SMFs). One core of the TCF is aligned with the cores of two segments of SMFs. An incident beam is directed into the TCF by the lead-in SMF. Light couples back and forth between two cores. The bend sensing performance of the sensor is investigated by intensity-modulated method. The intensity of the operation wavelength is modulated by the change of refractive index and geometrical deformation in the bent TCF. Experimental results show such a bend sensor achieves sensitivity of +0.671 /m-1 and resolution of 0.003âm-1 in the range of 0 to 1.25âm-1. In addition, the sensitivity and bend measurement range can be flexibly adjusted through selection of the length of TCF and sensing configuration. As such, the proposed sensor can be further developed for large or small bend ranges measurement.

15.
Dalton Trans ; 48(34): 12956-12963, 2019 Sep 14.
Artigo em Inglês | MEDLINE | ID: mdl-31396610

##### RESUMO

A praseodymium(iii)-containing arsenotungstate K16H15Li7[Pr2(H2O)3(pzdc)As3W29O103]2·38H2O (1) (pzdc = pyrazine-2,3-dicarboxylic acid) was synthesized by a conventional aqueous solution method and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single crystal X-ray diffraction. Structural analysis revealed that compound 1 was constructed by two identical subunits {Pr2(H2O)3(AsW9O33)3W2O4} bridged together by two pzdc ligands. In addition, compound 1 could act as an efficient catalyst for the epoxidation of olefins and oxidation of alcohols with hydrogen peroxide (H2O2) as the oxidant. In particular, the turnover frequency (TOF) in the oxidation of 1-phenylethanol reached up to 10 170 h-1, which is higher than that of previously reported catalysts.

16.
Sensors (Basel) ; 19(4)2019 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-30823608

##### RESUMO

In this paper, the correlation coefficients and the total scattering cross sections (TSCSs) for different types of metasurfaced stirrers and the traditional metallic stirrer, and the effects on field uniformity when such stirrers are used in reverberation chambers, are analyzed. Three metasurfaced stirrers are considered: A stirrer with two unit cells arranged alternatively (#1), a stirrer with two unit cells arranged in a chessboard-like manner (#2), and a stirrer with two unit cells in random arrangement (#3). From the correlation coefficient and TSCS results obtained in simulations, it follows that metasurfaced stirrer #1 is the best option. Field uniformity analysis of the resulting metasurface reverberation chambers (MRC) equipped with the different stirrers also supports this conclusion.

17.
Sensors (Basel) ; 18(10)2018 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-30275373

##### RESUMO

The use of metasurfaces to increase the number of modes, lower the operating frequency, and improve the field uniformity in reverberation chambers (RCs) is investigated in this paper. The method used to improve the field uniformity and decrease the resonance frequencies is based on increasing the number of modes by using the concept of subwavelength cavities. The resonance frequencies of a RC with metasurface wall are derived and expressed analytically in terms of macroscopic characteristics. Simulation of the reflection phase of the unit cell is then given as a guideline to choose the required microscopic parameters of the designed metasurface. The mode density in such subwavelength RCs is then obtained using a numerical eigenmode solver. Compared to traditional RCs, a much higher modal density is obtained at low frequencies. The standard deviation of the field uniformity in the test volume of the RC corresponding to different types of metasurface walls is finally compared. It is shown that by increasing the number of modes in the RC at the lower band, the operating frequency decreases and the field uniformity of the RC is improved.

18.
J Neurophysiol ; 115(2): 741-51, 2016 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-26609118