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Polymers (Basel) ; 11(12)2019 Nov 22.
Artigo em Inglês | MEDLINE | ID: mdl-31771097


Composites using agricultural and forestry residues as raw materials with potentially high-performance, multifunctional and biodegradable ecological advantages, are viewed as very promising for new-generation lightweight and low-cost bio-based sustainable building materials. At present, the research on wood-plastic composite materials is relatively mature. However, it is still a challenge to effectively use other biomass and improve the interface of the high-polymer compound system. Herein, we proposed a simple and effective method to enhance the interfacial adhesion properties of rice husk fibre and High Density Polyethylene (HDPE) composites by the silane coupling agent KH-550 and compatibilizer Maleic anhydride grafted polyethylene (MAPE) with complementary modification. It was found that the coupling agent KH-550 cross-linked with the hydroxyl group on the husk fibre surface and solidified with the high polymer by -NH-, -C=O- functional group generation. Compatibilizer MAPE strengthened the two phases by covalently bonding with an ester linkage and lowered the roughness of the cross-section of the composites. Meanwhile the modification enhanced the dispersibility, and mechanical properties of the husk-high polymer compound system, the bending and flexural strength were improved by 11.5% and 28.9% with KH-550, and MAPE added, respectively. The flexural strength of the composites increased by 40.7% after complementary modification. Furthermore, the complementary modification treatment reduced the hydrophilic hydroxyl groups and increased the molecular chain to improve the water-resistance, elastic modulus and toughness of the composite. This study prepared a bio-composite, which is expected to expand the use of agricultural and forestry residues as an extension of wood-plastic composites.

Materials (Basel) ; 12(21)2019 Oct 24.
Artigo em Inglês | MEDLINE | ID: mdl-31653050


Corn straw is a kind of biomass material with huge reserves, which can be used in plate processing, handicraft manufacturing, indoor decoration, and other fields. To investigate the dyeing mechanism of corn straw with different dyes, corn straw was pretreated and dyed with Acid Red GR and Brilliant Red X-3B. The dyeing properties and light resistance of the two dyes were analyzed by dyeing rate, photochromaticity, FTIR, SEM, and water-washing firmness. The results showed that the structure and stability of the dyes were the main factors which influenced fading. A bleaching pretreatment could remove the waxiness of the corn straw epidermis and increase the porosity on the surface of the straw, which accelerated the photochromic coloring of the corn straw skin. The corn straw dyed with both dyes had good light resistance, but the straw dyed with Reactive Brilliant Red X-3B had higher dyeing rate, brighter color, and higher photochromaticity than the straw dyed with Acid Red GR. FTIR and water-washing firmness showed that Acid Red GR mainly bound to lignin, while Reactive Brilliant Red X-3B mainly bound to cellulose, hemicellulose, and lignin in corn straw through covalent bonds, which increased the coloring rate.