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1.
Waste Manag ; 177: 232-242, 2024 Apr 01.
Artículo en Inglés | MEDLINE | ID: mdl-38342060

RESUMEN

Heterogeneity of pyrolytic parameters in municipal solid waste (MSW) significantly hinders its waste-to-energy efficiency. So far, hardly any light has been shed on current pyrolytic heterogeneity conditions or feasible pyrolytic homogeneity enhancement approaches of MSW. Accordingly, pyrolytic properties (Ea and logA) of 130 MSW samples in 6 categories were collected from literature. A kinetic parameters clustering-based sorting strategy for MSW was proposed. A so-called C index was established to compare their sorting performance for Ea and logA against two traditional sorting strategies (substance categorization and density clustering). Results showed that the proposed sorting strategies outperformed the traditional ones in pyrolytic homogeneity enhancement, where the optimal C_Ea and C_logA reached 1578.30 kJ/mol and 93.11 -log min. Among investigated clustering methods, k-means clustering outperformed hierarchical clustering, which could be attributed to its adaptability to the sample structure. Future perspectives involving data set expansion, model framework development, and downstream technologies matching were also discussed. The index C established in this study can be used to evaluate other clustering models.


Asunto(s)
Pirólisis , Residuos Sólidos , Análisis por Conglomerados , Cinética , Tecnología
2.
J Health Popul Nutr ; 43(1): 34, 2024 Feb 29.
Artículo en Inglés | MEDLINE | ID: mdl-38424610

RESUMEN

OBJECTIVE: Physical and mental health concerns and symptoms, including sleep problems, low mood, extreme tiredness, and appetite loss are prevalent among people living near waste sites. This research examines differences in health symptoms among residents living near municipal solid waste sites in the Ashanti Region, Ghana. METHODS: The study used cross-sectional data from 827 residents living near three municipal waste sites, including Besease, Asokore, and Dompoase sites in the Ashanti Region, Ghana. Descriptive statistics, Pearson's chi-square, and binary logistic regressions were performed to examine the differences and associations between the variables. RESULTS: Health symptoms, including sleep problems/insomnia, frequent extreme tiredness, low mood, loss of appetite, stress, anxiety, and depression, were reported by the majority of the participants. Residents near open dumpsites (Besease and Asokore) exhibit significantly higher likelihoods of experiencing various health symptoms such as extreme fatigue, depression, psychological disorders, thinking and concentration problems, low mood, loss of appetite, and anxiety compared to those near the engineered Oti landfill in Dompoase. CONCLUSION: While emphasizing the importance of proper landfill design and management in Ghana, this study underscores the need for further longitudinal and clinical investigations. Clinically establishing the link between dumpsites and health symptoms is imperative for informed public health interventions and policy decisions aimed at mitigating the potential adverse health effects of landfills on residents' well-being.


Asunto(s)
Trastornos del Sueño-Vigilia , Residuos Sólidos , Humanos , Estudios Transversales , Salud Mental , Ghana/epidemiología
3.
Waste Manag ; 178: 46-56, 2024 Apr 15.
Artículo en Inglés | MEDLINE | ID: mdl-38377768

RESUMEN

In a global context, the production of urban solid waste significantly varies with changes in living standards. This trend exhibits diversity across different countries and regions, reflecting shifts in lifestyles as well as varying needs and challenges in waste management strategies. However, current standards of waste recycling are too complex for the general public to follow. In this study, we propose a model called DSYOLO-Trash to identify solid waste by integrating the dual attention mechanisms convolutional block attention module (CBAM) and Contextual Transformer Networks(CotNet), which significantly enhance its ability to mine channel-related and spatial attention features while optimizing the learning process. We apply the deep simple online and realtime tracking (DeepSORT) object tracking algorithm to solid waste detection for the first time in the literature to enable the real-time identification and tracking of waste. We also develop a multi-label dataset of mixed solid waste, called MMTrash, to realistically simulate actual scenarios of waste classification. Our proposed DSYOLO-Trash delivered superior performance to classical detection algorithms on both the MMTrash and the TrashNet datasets. Our system combines the improved you only look once(YOLO) algorithm with DeepSORT technology by using industrial cameras and PLC-controlled robotic arms to intelligently sort waste. The work here constitutes an important contribution to intelligent waste management and the sustainable development of cities.


Asunto(s)
Residuos de Alimentos , Residuos Sólidos , Algoritmos , Ciudades , Suministros de Energía Eléctrica
4.
Environ Monit Assess ; 196(3): 308, 2024 Feb 26.
Artículo en Inglés | MEDLINE | ID: mdl-38407739

RESUMEN

Management of solid waste from rural hospitals is amongst problems affecting Zimbabwe due to diseases, population, and hospital increase. Solid waste from rural hospitals is receiving little attention translating to environmental health problems. Therefore, 101 secondary sources were used to write a paper aiming to proffer a hierarchical model to achieve sustainable solid waste management at rural hospitals. Rural hospitals' solid waste encompasses electronic waste, sharps, pharmaceutical, pathological, radioactive, chemical, infectious, and general waste. General solid waste from rural hospitals is between 77.35 and 79% whilst hazardous waste is between 21 and 22.65%. Solid waste increase add burden to nearly incapacitated rural hospitals. Rural hospital solid waste management processes include storage, transportation, treatment methods like autoclaving and chlorination, waste reduction alternatives, and disposal. Disposal strategies involve open pits, open burning, dumping, and incineration. Rural hospital solid waste management is guided by legislation, policies, guidelines, and conventions. Effectiveness of legal framework is limited by economic and socio-political problems. Rural hospital solid waste management remain inappropriate causing environmental health risks. Developed hierarchical model can narrow the route to attain sustainable management of rural hospitals' solid waste. Proposed hierarchical model consists of five-layered strategies and acted as a guide for identifying and ranking approaches to manage rural hospitals' solid waste. Additionally, Zimbabwean government, Environmental Management Agency and Ministry of Health is recommended to collaborate to provide sufficient resources to rural hospitals whilst enforcing legal framework. Integration of all hierarchical model's elements is essential whereas all-stakeholder involvement and solid waste minimisation approaches are significant at rural hospitals.


Asunto(s)
Residuos Electrónicos , Residuos Sólidos , Zimbabwe , Monitoreo del Ambiente , Hospitales
5.
Waste Manag ; 178: 292-300, 2024 Apr 15.
Artículo en Inglés | MEDLINE | ID: mdl-38422682

RESUMEN

Clean up following the wide-area release of a persistent biological agent has the potential to generate significant waste. Waste containing residual levels of biological contaminants may require off-site shipment under the U.S. Department of Transportation's (US DOT) solid waste regulations for Category A infectious agents, which has packaging and size limitations that do not accommodate large quantities. Treating the waste on-site to inactivate the bio-contaminants could alleviate the need for Category A shipping and open the possibility for categorizing the waste as conventional solid waste with similar shipping requirements as municipal garbage. To collect and package waste for on-site treatment, a semi-permeable nonwoven-based fabric was developed. The fabric was designed to contain residual bio-contaminants while providing sufficient permeability for penetration by a gaseous decontamination agent. The nonwoven fabric was tested in two bench-scale experiments. First, decontamination efficacy and gas permeability were evaluated by placing test coupons inoculated with spores of a Bacillus anthracis surrogate inside the nonwoven material. After chlorine dioxide fumigation, the coupons were analyzed for spore viability and results showed a ≥6 Log reduction on all test materials except glass. Second, filters cut from the nonwoven material were tested in parallel with commercially available cellulose acetate filters having a known pore size (0.45 µm) and results demonstrate that the two materials have similar permeability characteristics. Overall, results suggest that the nonwoven material could be used to package waste at the point of generation and then moved to a nearby staging area where it could be fumigated to inactivate bio-contaminants.


Asunto(s)
Bacillus anthracis , Residuos Sólidos , Esporas Bacterianas/fisiología , Descontaminación/métodos
6.
J Environ Manage ; 354: 120362, 2024 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-38364543

RESUMEN

In order to tackle the environmental problems induced by Portland cement production and industrial solid wastes landfilling, this study aims to develop novel ternary cementless fly ash-based geopolymer by recycling red mud and blast furnace slag industrial solid wastes. The fresh-state properties, mechanical strength, water permeability, phase assemblage and microstructure were systematically investigated to evaluate the performance variation and reveal the hydration mechanism for geopolymers with different mixing proportions. The results showed that a higher slag content or a lower red mud content could result in the higher fluidity and shorter setting time for fresh mixture. The existence of slag promoted the transformation of N-A-S-H to C-A-S-H gel, which contributed to higher compressive strength and better resistance to water penetration. However, an excessive incorporation of 30% red mud may impede the generation of N-A-S-H gel and form more flocculent-like loose hydrates, thus to mildly degrade the mechanical strength and anti-permeability. The synergetic utilization of red much and blast furnace slag in fly ash-based geopolymer led to much less CO2 emission compared with the condition that red much or slag was singly added, which demonstrated prominent environmental advantages for such kind of ternary cementless geopolymer with equivalent mechanical strength.


Asunto(s)
Ceniza del Carbón , Residuos Sólidos , Ceniza del Carbón/química , Carbono/química , Residuos Industriales/análisis , Agua
7.
Environ Monit Assess ; 196(2): 225, 2024 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-38300328

RESUMEN

Considering the lack of an in-depth and comprehensive study on slaughter waste quantification and its management, despite the growing demand for meat this study aims to quantify the slaughter waste generated in Mumbra, Thane, India, from the meat retail stores. The study also endeavors to find the composition of slaughter waste in municipal solid waste by employing the questionnaire survey method. The literature reviewed the published studies on the life cycle analysis of food products for global warming potential values for meat and vegetable products along with the vegetarian and non-vegetarian dietary patterns. In this study, it was observed that 55.93% of the population were non-vegetarian consumers and the composition of slaughter waste was 7% of total municipal solid waste disposed of in disposal sites resulting in greenhouse gas emission of 0.11 Gg CO2 Eq./year. The study presents the implementation of a biomethanation plant as a mitigation measure, along with an evaluation of the theoretical biogas potential and electricity generation capacity derived from slaughter waste, considering it as a potential feedstock. The outcomes of this study also highlight the necessity for further focused research in this specific area, aiming to increase consumer knowledge regarding the environmental impacts of meat-based diets. The finding of this study will help researchers and assists policymakers in facilitating effective management and understanding the scale of the emissions resulting from meat products and slaughter waste and identifying suitable mitigation approaches, and actively contributing to reducing the environmental footprint.


Asunto(s)
Monitoreo del Ambiente , Residuos Sólidos , Animales , Biocombustibles , Estadios del Ciclo de Vida
8.
Waste Manag ; 177: 1-12, 2024 Apr 01.
Artículo en Inglés | MEDLINE | ID: mdl-38281469

RESUMEN

Rapid economic development inevitably leads to the discharge of a large amount of common industrial solid waste (CISW), which not only pollutes the environment but also restricts economic development in turn. In this study, a dynamic common industrial solid waste (DCISW) model is developed to analyze the retrospectively CISW development in Shanghai from 2000 to 2017 and simulate prospectively multi-perspective emission reduction measures. Specifically, the dynamic linkages between CISW and socio-economics are established at both the systematic and sectoral levels through input-output analysis, ecological network analysis, and related socio-economic indicators. Abatement measure simulations are conducted using RAS and other methods. The findings reveal that the growth of CISW in Shanghai is closely related to its fast-growing economy. The Others sector (OS) receives the most CISW from other sectors, while the Mining industry (MI) sends the most CISW to others. From production-based, consumption-based, and income-based perspectives, Chemical Products (CP) consistently remain the largest contributors. For the proposed waste generation intensity (WGI) indicator, the Mining industry (MI) is regarded as the main sector in all three perspectives. Moreover, the MI consistently emerges as the key sector of the system. CISW simulations indicate that improving the MI emission technology and increasing the MI output value will be top priorities for CISW emission reduction in Shanghai. This study is expected to provide scientific support to address the CISW problem in Shanghai and other similar fast-growing metropolises.


Asunto(s)
Industrias , Residuos Sólidos , China , Estudios Retrospectivos , Desarrollo Económico , Residuos Industriales
9.
Bioresour Technol ; 394: 130289, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-38181997

RESUMEN

This study explores the viability of utilizing municipal solid waste (MSW) and legacy waste as a renewable energy source through pyrolysis, akin to solid fuels. The heating value of MSW and legacy waste were found to be 37737.89 and 40432.84 kJ/kg, respectively. Proximate analysis shows that MSW fits within Tanner diagram parameters, eliminating the need for auxiliary fuel in pyrolysis. With 47.6 % and 44.16 % lignin content in MSW and legacy waste were deemed suitable for char production. Thermal degradation resulted in mass losses of 68 % for MSW and 82 % for legacy waste. The kinetic and thermodynamic assessment indicates lower activation energy (Ea) and Gibbs free energy (ΔG) for MSW (5.72 kJ/mol and 170.37 kJ/mol, respectively) compared to fossil fuels, suggesting faster reactions without additional energy requirement. MSW emerges as a promising alternative to fossil fuels, aligning with the United Nations' 2030 Sustainable Development Goals.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Residuos Sólidos/análisis , Pirólisis , Fuentes Generadoras de Energía , Energía Renovable , Combustibles Fósiles/análisis
10.
Bioprocess Biosyst Eng ; 47(2): 235-247, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-38170236

RESUMEN

This paper presents the analysis of a pilot anaerobic digestion plant that operates with organic fraction of municipal solid waste (OFMSW) from a wholesale market and can treat up to 500 kg d-1. The process was monitored for a period of 524 days during which the residue was characterized and the biogas production and methane content were recorded. The organic load rate (OLR) of volatile solids (VS) was 0.89 kg m-3 d-1 and the Hydraulic Retention Time (HRT) was 25 d during the process. The yield was 82 Nm3 tons OFMSW-1 biogas, equivalent to 586 Nm3 tons CH4 VS-1. The results obtained in the pilot plant were used to carry out a technical-economic evaluation of a plant that treats 50 tons of OFMSW from wholesale markets. A production of 3769 Nm3 d-1 of biogas and 2080 Nm3 d-1 of methane is estimated, generating 35.1 MWh d-1 when converted to electricity.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Residuos Sólidos/análisis , Eliminación de Residuos/métodos , Anaerobiosis , Biocombustibles , Reactores Biológicos , Metano
11.
Sci Total Environ ; 915: 170083, 2024 Mar 10.
Artículo en Inglés | MEDLINE | ID: mdl-38224881

RESUMEN

Leachate is a highly complex waste with high toxicological potential that poses a significant threat to the terrestrial environment. Determining leachate physicochemical parameters and identifying xenobiotics alone is, however, not enough to determine the real environmental impacts. In this context, the use of terrestrial model organisms has been highlighted as a tool in ecotoxicological leachate assessments and as a guiding principle in risk assessments. In this context, this review aimed to present the most current state of knowledge concerning leachate toxicity and the bioassays employed in this evaluation concerning terrestrial plants and animals. To this end, a literature search on leachate effects on terrestrial organisms was carried out using ten search terms, in 32 different combinations, at the Web of Science and Scopus databases. A total of 74 eligible articles were selected. The retrieved studies analyzed 42 different plant and animal species and employed nine endpoints, namely phytotoxicity, genotoxicity, bioaccumulation, antioxidant system, cytotoxicity, reproduction, physiological changes, behavior and lethality. A frequent association of toxic leachate effects with metals was observed, mainly Pb, Cd, Cr, Mg, Zn and Cr, which can cause antioxidant system alterations and cyto- and genotoxicity. These elements have also been associated to reproductive effects in earthworms and mice. Specifically concerning plants, most of the retrieved studies employed Allium cepa in toxicity assays, reporting phytotoxic effects frequently associated to metals and soil parameter changes. Animal studies, on the other hand, mostly employed mice and evaluated genotoxicity and antioxidant system effects. Even with the description of toxic leachate effects in both plants and animals, a lack of knowledge is still noted concerning reproductive, physiological, cytotoxic, and behavioral effects in terrestrial species. We, thus, suggest that further studies be carried out on other animals, advancing our understanding on potential environmental leachate effects, also allowing for human health risk assessments.


Asunto(s)
Residuos Sólidos , Contaminantes Químicos del Agua , Humanos , Animales , Ratones , Residuos Sólidos/análisis , Antioxidantes/farmacología , Plantas , Cebollas , Metales , Contaminantes Químicos del Agua/análisis
12.
Waste Manag ; 176: 74-84, 2024 Mar 15.
Artículo en Inglés | MEDLINE | ID: mdl-38266477

RESUMEN

Aeration plays a crucial role in accelerating the secondary compression of municipal solid waste (MSW) for the scientific implementation of aerobic bioreactor technology. There are few comparative reports on the secondary compaction characteristics of MSW in aerobic and anaerobic bioreactors. In this study, six long-term compression tests were conducted to analyze the impact of aeration on MSW compression characteristics, considering two degradation conditions (i.e. aerobic and anaerobic conditions) and three overburden stresses (i.e. 30, 50 and 100 kPa). Model-fitting analysis was employed to examine the data from the tests and exiting literatures. The results showed that aeration effectively increased the rate of secondary compression, and slightly enhanced the steady-state secondary compression strain. In addition, these enhancements tended to decrease with increasing stresses. The increment ratio of the secondary compression rate constant (Rk) was concentrated in the range of 25 % to 100 %, and increases with the increase of aeration rate. The increment ratio of the steady-state secondary compression strain (Rε) ranged from 10 % to 90 %, for the MSW with higher content of paper and wood exhibited higher Rε. The advance ratio of the secondary compression stabilization time (Rt) fell within the range of 20-50 %, and Rt is higher when the moisture content is in the range of 50-65 %. These findings provide valuable guidance on the accelerated stabilization in aerobic bioreactors, providing practical references for the application of aerobic technology to informal landfills.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Residuos Sólidos/análisis , Eliminación de Residuos/métodos , Anaerobiosis , Reactores Biológicos , Instalaciones de Eliminación de Residuos
13.
Waste Manag ; 176: 159-168, 2024 Mar 15.
Artículo en Inglés | MEDLINE | ID: mdl-38281347

RESUMEN

Pyrolysis is a promising method for recovering resources and energy products from municipal solid waste (MSW). Predicting MSW pyrolysis products is crucial for establishing an efficient pyrolysis system for resource recovery. In this study, a database was established based on MySQL to record relevant information on MSW pyrolysis, which includes the MSW ultimate analysis results, proximate analysis results, parameters of pyrolysis operation and yields of pyrolysis products, etc. Based on the database and with help of a deep artificial neural network (ANN) which contains 10 hidden layers, a prediction model was successfully established to predict the yield of char, liquid and gas products from MSW pyrolysis. The results showed that the coefficients of determination for predicting the yields of char, liquid and gas from the MSW pyrolysis are 0.841, 0.84, and 0.85, respectively; these values demonstrate an accuracy comparable to that achieved for product prediction from single biomass, indicating a successful model performance. The results also show that ash content and temperature are the most important input factors influencing the outputs, namely, yields of char, liquid and gas. The results of this study can help to achieve a more efficient design of the pyrolysis system and improve the recovery of the desired pyrolysis products.


Asunto(s)
Pirólisis , Residuos Sólidos , Residuos Sólidos/análisis , Temperatura , Redes Neurales de la Computación , Biomasa
14.
Environ Res ; 246: 118121, 2024 Apr 01.
Artículo en Inglés | MEDLINE | ID: mdl-38184063

RESUMEN

The current study aims to examine the techno-economic and environmental assessment of biorefinery development within a circular bioeconomy context by using an organic fraction of municipal solid waste (OFMSW) by extraction of lipids, carbohydrates, and proteins with 98, 51 and 62 % by mass of conversion efficiency and yield recovery, and value-added fractions production as well. Fatty acid methyl ester (biodiesel) and glycerol (biofuel) were produced by applying transesterification process, and the remaining biomass was converted into biocrude oil by thermal liquefication. The biorefinery using 613 kg of OFMSW produced biodiesel, glycerol, and bioethanol with 126 litter, 14.3 kg, and 172 litter respectively, as well as value-added fractions, such as biocrude oil with 78 kg. The environmental impact was assessed using the life cycle assessment (LCA) framework, ReCiPe2016 Mid-point (H) approach, through 18 different environmental categories. The key findings elucidate that Terrestrial ecotoxicity, Climate change, Fossil depletion and Human toxicity were the main impact categories which are potentially contributed 9.81E+02 kg 1,4-DB eq., 1.43E+03 kg CO2 eq., 2.04E+02 kg oil eq., and 8.08E+01 kg 1,4-DB eq. The normalization (person per equivalent) analysis revealed that only categories of resource reduction (fossil and metal depletion) are the key contributors to environmental degradation. The biorefinery system's total revenue was estimated at USD 6.817,509 million annually. The calculated revenue was USD 0.026 million daily in a shift of 8 h. The Net present worth (NPW) was calculated at USD 499.97 million by assuming a discount factor of 10 % and inflation rate of 5 % for 15 years. The project is considered feasible by demonstrating 7.15 payback year. This research showcased the efficient portrayal of the biorefinery system and succinctly conveyed the significant circular bioeconomy for a greener future. Thus, it could be helpful to the stakeholder's context towards techno-economic and environmental evaluation.


Asunto(s)
Biocombustibles , Residuos Sólidos , Humanos , Residuos Sólidos/análisis , Biocombustibles/análisis , Glicerol , Ambiente , Biomasa
15.
Environ Pollut ; 344: 123417, 2024 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-38253163

RESUMEN

The study concerned technical feasibility, economic profitability, and carbon footprint (CF) analysis of semi-continuous anaerobic digestion (sAD) of organic fraction of municipal solid waste (OFMSW). The research assessed the pre-treatment effect on sAD by varying organic loading rates (OLR) from 3.38 to 6.75 kgvs/m3d. Three sAD configurations were investigated: hydrodynamic-cavitated (HC-OFMSW), enzymatically pre-treated (EN-OFMSW), and non-pre-treated (AD-OFMSW). Principal Component Analysis and Supervised Kohonen's Self-Organizing Maps combined the experimental, economic, and environmental evaluations. The sAD configurations were grouped predominantly according to the OLR however, within each OLR group the configurations were clustered according to the pre-treatments. The finding highlighted that pre-treatments offset inhibition in sAD of OFMSW due to the OLR increase, being economically profitable and CF negative up to 4.50 kgvs/m3d for EN-OFMSW and to 5.40 kgvs/m3d for HC-OFMSW. Whereas sAD-OFMSW remained economically and environmentally viable only up to 3.87 kgvs/m3d. HC-OFMSW reached the highest performance. In detail, for HC-OFMSW the NPV and CF ranged from 17679.30 to 43827.12 euros and from -51.08 to -407.210 kg CO2eq/1 MWh daily produced, by decreasing the OLR from 5.40 to 3.87 kgvs/m3d. These results are fundamental since pre-treatment is usually expensive due to additional energy or chemical requirements.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Análisis Costo-Beneficio , Anaerobiosis , Algoritmos , Hidrodinámica , Reactores Biológicos , Metano
16.
Environ Sci Pollut Res Int ; 31(9): 14156-14177, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-38277108

RESUMEN

This study aimed to assess the suitability of the potential solid waste landfill sites in seven provinces (Samsun, Ordu, Giresun, Trabzon, Gümüshane, Bayburt and Artvin) in the Eastern Blacksea Region of Türkiye. The earthquake hazard analysis for two major earthquakes which occurred in the region was first carried out. Then, the geophysical methods including seismic refraction tomography (SRT), electrical resistivity tomography (ERT) and Multichannel Analysis of Surface Waves (MASW) were conducted to find out the structural and physical properties of the subsurface which include the layering, soil classification based on VS30 and the groundwater content at 25 locations of 13 in target provinces. The integrated interpretation of whole data sets demonstrates that Isiktepe, Esence, Çamburnu and Kazantas which are characterized by VP > 1200 m/s, VS30 ≥ 400 m/s, ρ > 70 Ohm-m, low earthquake hazard and seismicity are more suitable among others. Vezirköprü, Sebinkarahisar, Yenice, Bayburt-Center, Balkaynak and Murgul will be suitable after a geotechnical reclamation due to moderate seismic velocities and electrical resistivity which are 900 < VP ≤ 1200 m/s, 200 < VS30 < 400 m/s and 10 < ρ ≤ 70 Ohm-m representing stiff and wet soils. In addition, Bafra, Agalik and Ovacik were considered to be unsuitable due to the presence of thick, water-saturated soft soil and extremely weathered rocks. Finally, this study shows that the joint interpretation of seismicity and geophysical data in potential waste landfill sites, extremely important for the planning and development of a city, can provide the valuable information which will enable to prevent possible deformations, environmental problems and economic losses after waste landfill.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Eliminación de Residuos/métodos , Monitoreo del Ambiente/métodos , Mar Negro , Turquia , Instalaciones de Eliminación de Residuos , Suelo
17.
J Environ Manage ; 353: 120020, 2024 Feb 27.
Artículo en Inglés | MEDLINE | ID: mdl-38278115

RESUMEN

Dredged soil and phosphogypsum (PG) are waste materials that must be treated to reduce their negative environmental effects. Guided by the concept of waste treatment, this study proposed the use of PG as a supplementary cementitious material to stabilize waste-dredged soil, and calcium aluminate cement (CAC) was selected to further improve the strength of the cement-treated dredged soil. Several laboratory tests were conducted to investigate the pH, unconfined compressive strength (UCS), and failure strain of the cement-treated soils in different proportions. Microstructural and mineralogical tests were performed to reveal the mechanisms underlying the strength improvement of PG and CAC. The results showed that both PG and CAC enhanced the strength of cement-treated dredged soil. PG provided SO2- 4 to promote the formation of ettringite (aluminum ferrite trisulfate (AFt)), whereas CAC neutralized the acidity of PG and provided reactants to the reaction system, leading to an increase in the pH and strength with an increase in the relative CAC content. Meanwhile, an exponential relationship was obtained between pH and qu. Mineralogical changes demonstrated that the major hydration products of cementitious materials, such as calcium silicate (aluminate) hydrate (C-(A)-S-H), AFt, and calcium aluminate hydrate (C-A-H), enhanced the strength by filling pores between particles and bridging soil particles. However, excess CAC content may not be favorable for the later strength formation, the relative CAC content is recommended to be in the range of 40%-60%. Compared to using sand, the construction of a square kilometer of reclamation consumed 3.5 million tons of PG, and saved 1.54 billion USD by using dredged soil as raw material. Hence, the use of PG to treat dredged soils will have great environmental sustainability, economic benefits, and engineering value.


Asunto(s)
Compuestos de Aluminio , Compuestos de Calcio , Fósforo , Suelo , Residuos Sólidos , Sulfato de Calcio
18.
Bioengineered ; 15(1): 2307668, 2024 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-38265757

RESUMEN

Enzymatic hydrolysis of organic waste is gaining relevance as a complementary technology to conventional biological treatments. Moreover, biorefineries are emerging as a sustainable scenario to integrate waste valorization and high-value bioproducts production. However, their application on municipal solid waste is still limited. This study systematically evaluates the techno-economic feasibility of the conversion of the organic fraction of municipal solid waste (OFMSW) into high-value bioproducts through enzymatic hydrolysis. Two key variables are examined: (a) the source of the enzymes: commercial or on-site produced using OFMSW, and (b) the treatment of the solid hydrolyzate fraction: solid-state fermentation (SSF) for the production of biopesticides or anaerobic digestion for the production of energy. As a result, four different biorefinery scenarios are generated and compared in terms of profitability. Results showed that the most profitable scenario was to produce enzymes on-site and valorize the solid fraction via SSF, with an internal rate of return of 13%. This scenario led to higher profit margins (74%) and a reduced payback time (6 years), in contrast with commercial enzymes that led to an unprofitable biorefinery. Also, the simultaneous production of higher-value bioproducts and energy reduced the economic dependence of OFMSW treatment on policy instruments while remaining energetically self-sufficient. The profitability of the biorefinery scenarios evaluated was heavily dependent on the enzyme price and the efficiency of the anaerobic digestion process, highlighting the importance of cost-efficient enzyme production alternatives and high-quality OFMSW. This paper contributes to understanding the potential role of enzymes in future OFMSW biorefineries and offers economical insights on different configurations.


Techno-economic analysis to assess enzyme origin and solid hydrolysate fate.The viability of enzymatic hydrolysis depends on the cost and origin of enzymes.On-site produced enzymes cut payback time to 6 years, elevating profits by 74%.Anaerobic digestion and solid-state fermentation can be complementary technologies.High-value bioproducts are key to making organic waste biorefineries profitable.


Asunto(s)
Agentes de Control Biológico , Residuos Sólidos , Anaerobiosis , Fermentación , Hidrólisis
19.
Waste Manag ; 175: 62-72, 2024 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-38171077

RESUMEN

CO2 mineral sequestration using alkaline solid waste (ASW) is a promising strategy for synergistically reducing CO2 emissions and reusing industrial waste. However, improvement the carbonation degree still remains challenges due to the sluggish leaching rate of Ca/Mg ion at low pH. To the issues, this study proposed an amine-mediated CO2 absorption and mineralization process with six common ASWs, as well an ecological utilization route of CO2-ASW productions. Experimental results indicated that calcium carbide slag (CS) had greater CO2 mineralization capacity (86.2 g-CO2/kg-CS) than other ASWs, while stirring rate and particle size played a more important role during CO2 capture. Amine-mediated CO2 capture was verified to be more excellent with steel slag (SS) as mineral medium. When the MEA concentration was increased to 2 mol/L, the extraction efficiency of Ca2+ was increased by 35 %, leaded to the CO2 removal efficiency significantly promoted from 49 % to 92 %. The characterization of structural morphology referred spherical aragonite or needle-bar calcite was dominant for the porous mineralization products (30.6 m2/g). High germination index of pea seed (112.1 % at a dose of 10 g/L) inferred the negligible toxicological effects of tiny MEA residue over SS mineralization products, after centrifugally washing treatment. Pea seeds cultivated with mineralized products after centrifugal washing can achieve a growth rate of about 4 mm/d. Overall, this work provides a feasible route to apply the porous CO2-ASWs production into water conservation in arid and sandy land.


Asunto(s)
Dióxido de Carbono , Residuos Sólidos , Dióxido de Carbono/química , Carbonato de Calcio/química , Residuos Industriales/análisis , Minerales/química , Acero/química , Aminas
20.
Environ Sci Pollut Res Int ; 31(7): 9948-9963, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-37072590

RESUMEN

In the process of marketization, the lack of redundancy evaluation of the MSW incineration treatment capacity leads to the regional imbalance of treatment capacity and waste of resources. Therefore, this study aimed to develop a spatial-temporal redundancy evaluation method for the MSW incineration treatment capacity based on the accurate MSW generation prediction using artificial intelligence. To achieve this aim, this study first proposed and finalized a prediction model of the provincial MSW generation by applying the artificial neuron network (ANN) technology and using the statistical data of Jiangsu Province of China from 1990 to 2020. In the finalized model, the input variables consist of three demographic variables, three social variables, and five economic variables; the model structure that includes four hidden layers and 16 neurons in each hidden layer performed best with a coefficient of determination (R2) of 0.995 on the training samples and an R2 of 0.974 on the test set, respectively. Using the finalized model and statistical data of all provinces in China, this study proposed a redundancy evaluation method for the MSW incineration treatment capacity and evaluated the spatial and temporal redundancy status of China. The results first confirm the effectiveness of the proposed method to model and quantify the redundancy problem. Second, according to the evaluation results, even if no new treatment plant will be built before 2025, 10 of China's 31 provinces still have redundancy problems, indicating the severity of this problem. This study first contributes to the body of knowledge by modeling the redundancy problem of the MSW incineration treatment capacity. Moreover, this study provides a tool to quantify temporal and spatial redundancy using advanced technology and publicly available data. Furthermore, the results can help waste-related authorities and organizations make optimal strategies and actions to better match MSW treatment capacity and MSW generation volume.


Asunto(s)
Eliminación de Residuos , Residuos Sólidos , Residuos Sólidos/análisis , Inteligencia Artificial , Incineración , Conservación de los Recursos Naturales , China
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