1,4,7,10-tetraoxacyclododecane-triphenylmethanethiol (1/2).
Acta Crystallogr C
; 61(Pt 7): o431-3, 2005 Jul.
Article
in En
| MEDLINE
| ID: mdl-15997075
ABSTRACT
In the centrosymmetric formula unit of the title complex, C8H16O4.2C18H16S, the 1,4,7,10-tetraoxacyclododecane molecule adopts the biangular [66] conformation, and the triphenylmethanethiol molecules are linked to the macrocycle via a long S-H...O hydrogen bond [S...O = 3.460 (2) A and S-H...O = 161 (2) degrees]. Attractive interactions of phenyl groups in edge-to-face conformations combine inversion-related formula units into chains running along the [111] direction in the crystal structure. Association of the chains into sheets is achieved via C-H...pi interactions.
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Collection:
01-internacional
Database:
MEDLINE
Main subject:
Sulfhydryl Compounds
/
Trityl Compounds
Language:
En
Journal:
Acta Crystallogr C
Year:
2005
Document type:
Article
Affiliation country: