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Shape-persistent elliptic macrocycles composed of polycyclic aromatic hydrocarbons: synthesis and photophysical properties.
Liu, Wen-Jun; Zhou, Yan; Zhou, Qi-Feng; Ma, Yuguo; Pei, Jian.
Affiliation
  • Liu WJ; The Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.
Org Lett ; 10(11): 2123-6, 2008 Jun 05.
Article in En | MEDLINE | ID: mdl-18452303
ABSTRACT
Bimolecular coupling/unimolecular cyclization strategies, including McMurry- and Glaser-type homocoupling reactions, were utilized to synthesize two shape-persistent elliptic macrocycles, which consist of polycyclic aromatic hydrocarbon units. The identity and purity of both macrocycles MC1 and MC2 were verified by 1H and 13C NMR, elemental analysis, as well as MALDI-TOF MS. The photophysical properties of MC1 and MC2 in dilute solution were also investigated.
Subject(s)

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Polycyclic Aromatic Hydrocarbons / Macrocyclic Compounds Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2008 Document type: Article Affiliation country:

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Polycyclic Aromatic Hydrocarbons / Macrocyclic Compounds Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2008 Document type: Article Affiliation country: