Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis.
Chem Commun (Camb)
; (35): 5227-9, 2009 Sep 21.
Article
in En
| MEDLINE
| ID: mdl-19707628
ABSTRACT
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF(6)], the precursor of [RuCp(CH(3)CN)(3)][PF(6)], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2009
Document type:
Article
Affiliation country: