Bis{(E)-2-[1-(eth-oxy-imino)-eth-yl]-1-naphtho-lato-κN,O}copper(II).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 12): m1626, 2010 Nov 24.
Article
in En
| MEDLINE
| ID: mdl-21589300
In the title complex, [Cu(C(14)H(14)NO(2))(2)], the discrete complex mol-ecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu(II) atom comprises two phenolate O atoms and two oxime N atoms from two bidentate-chelate 2-[1-(eth-oxy-imino)-eth-yl]-1-naphtho-late O-ethyl oxime (L(-)) ligands [Cu-O = 1.8919â
(17)â
Å and Cu-N = 1.988â
(2)â
Å]. The two naphthalene ring systems in the mol-ecule are parallel, with a perpendicular inter-planar spacing of 1.473â
(2)â
Å, while each complex unit forms links to four other mol-ecules via inter-molecular methyl C-Hâ¯π inter-actions, giving an infinite cross-linked layered supra-molecular structure.
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Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2010
Document type:
Article
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