Multicycle water vapour stability of microporous breathing MOF aluminium isophthalate CAU-10-H.
Dalton Trans
; 43(41): 15300-4, 2014 Nov 07.
Article
in En
| MEDLINE
| ID: mdl-25189376
ABSTRACT
The hydrothermal stability of aluminium hydroxide isophthalate MOF CAU-10-H was proven, under humid multi-cycling conditions. Detailed in situ thermogravimetric measurements and in situ powder X-ray diffraction analysis during water ad-/desorption were used. A reversible structural change during adsorption was detected and thereby exemplified the robustness of breathing-like MOFs over 700 water vapour ad/desorption cycles. In combination with high water adsorption capacity, hydrophilic CAU-10-H is the first breathing-like MOF with a structural change which is a promising candidate for the use in heat transformation processes.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2014
Document type:
Article