Homochiral metal-organic frameworks with enantiopure proline units for the catalytic synthesis of ß-lactams.
Inorg Chem
; 53(22): 12199-204, 2014 Nov 17.
Article
in En
| MEDLINE
| ID: mdl-25361035
ABSTRACT
Two enantiopure organic ligands integrating flexible proline units and rigid isophthalate units have been rationally designed and employed for the construction of four homochiral porous metal-organic frameworks (MOFs), respectively. One pair of these MOFs is used as heterogeneous catalysts to construct ß-lactam derivatives by oxidative coupling reactions.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Organometallic Compounds
/
Proline
/
Copper
/
Beta-Lactams
Language:
En
Journal:
Inorg Chem
Year:
2014
Document type:
Article