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First water-soluble backbone Ru-Ru-Ni heterometallic organometallic polymer.
Scalambra, Franco; Serrano-Ruiz, Manuel; Romerosa, Antonio.
Affiliation
  • Scalambra F; Área de Química Inorgánica-CIESOL, Universidad de Almería, 04120, Almería, Spain.
Macromol Rapid Commun ; 36(7): 689-93, 2015 Apr.
Article in En | MEDLINE | ID: mdl-25739739
ABSTRACT
The water-soluble backbone heterometallic polymer {[(PTA)2 CpRu-µ-CN-RuCp(PTA)2 -µ-NiCl3 ]}n (2) is synthesized using a reproducible and robust method and fully characterized by X-ray single crystal diffraction. The Ru-Ru-Ni polymer is found to be stable in the solid state and soluble in water. Nuclear magnetic resonance (NMR) and light scattering studies show that the polymer is stable in water for several days in air.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Polymers / Ruthenium Language: En Journal: Macromol Rapid Commun Year: 2015 Document type: Article Affiliation country:
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Polymers / Ruthenium Language: En Journal: Macromol Rapid Commun Year: 2015 Document type: Article Affiliation country: