Dinuclear oxidative addition reactions using an isostructural series of Ni2, Co2, and Fe2 complexes.
Dalton Trans
; 46(17): 5493-5497, 2017 May 02.
Article
in En
| MEDLINE
| ID: mdl-27996067
ABSTRACT
A family of low-valent Ni2, Co2, and Fe2 naphthyridine-diimine (NDI) complexes is presented. Ligand-based π* orbitals are sufficiently low-lying to fall within the metal 3d manifold, resulting in electronic structures that are highly delocalized across the conjugated [NDI]M2 system. This feature confers stability to metal-metal interactions during two-electron redox reactions, as demonstrated in a prototypical oxidative addition of allyl chloride.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2017
Document type:
Article
Affiliation country: