Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids.
Chem Commun (Camb)
; 53(81): 11154-11156, 2017 Oct 18.
Article
in En
| MEDLINE
| ID: mdl-28890962
ABSTRACT
We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2017
Document type:
Article
Affiliation country: