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Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate.
Benito, Quentin; Balogh, Cristina M; El Moll, Hani; Gacoin, Thierry; Cordier, Marie; Rakhmatullin, Aydar; Latouche, Camille; Martineau-Corcos, Charlotte; Perruchas, Sandrine.
Affiliation
  • Benito Q; Laboratoire de Physique de la Matière Condensée (PMC), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
  • Balogh CM; Laboratoire de Physique de la Matière Condensée (PMC), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
  • El Moll H; Laboratoire de Physique de la Matière Condensée (PMC), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
  • Gacoin T; Laboratoire de Physique de la Matière Condensée (PMC), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
  • Cordier M; Laboratoire de Chimie Moléculaire (LCM), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
  • Rakhmatullin A; CEMHTI-CNRS, UPR 3079, 1D avenue de la recherche scientifique, 45071, Orléans Cedex 2, France.
  • Latouche C; Present address for S. Perruchas: Institut des Matériaux de Nantes, 2 rue de la Houssinière, 44322 Cedex 3, France.
  • Martineau-Corcos C; CEMHTI-CNRS, UPR 3079, 1D avenue de la recherche scientifique, 45071, Orléans Cedex 2, France.
  • Perruchas S; MIM, Institut Lavoisier de Versailles (ILV), UMR CNRS 8180, Université de Versailles St-Quentin en Yvelines (UVSQ), 45, avenue des Etats-Unis, 78035, Versailles Cedex, France.
Chemistry ; 24(71): 18868-18872, 2018 Dec 17.
Article in En | MEDLINE | ID: mdl-30259587
ABSTRACT
A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2 I2 (Ph2 PC2 (C6 H4 )C2 PPh2 )3 ] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2018 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2018 Document type: Article Affiliation country: