Designed asymmetric coordination helicates with bis-ß-diketonate ligands.
Dalton Trans
; 48(45): 16844-16847, 2019 Dec 07.
Article
in En
| MEDLINE
| ID: mdl-31681934
ABSTRACT
A new bis-(ß-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(iii) and Ga(iii) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2019
Document type:
Article
Affiliation country: