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2 H and 13 C NMR-Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists.
Lesot, Philippe; Berdagué, Philippe; Meddour, Abdelkrim; Kreiter, Alexander; Noll, Markus; Reggelin, Michael.
Affiliation
  • Lesot P; RMN en Milieu Orienté, ICMMO, UMR CNRS 8182, Université Paris Sud/Université Paris-Saclay, Bât. 410, 91405, Orsay cedex, France.
  • Berdagué P; RMN en Milieu Orienté, ICMMO, UMR CNRS 8182, Université Paris Sud/Université Paris-Saclay, Bât. 410, 91405, Orsay cedex, France.
  • Meddour A; RMN en Milieu Orienté, ICMMO, UMR CNRS 8182, Université Paris Sud/Université Paris-Saclay, Bât. 410, 91405, Orsay cedex, France.
  • Kreiter A; Clemens-Schöpf-Institut für Organische Chemie und Biochemie, Technische Universität Darmstadt, Alarich-Weiss-Strasse 4, 64287, Darmstadt, Germany.
  • Noll M; Clemens-Schöpf-Institut für Organische Chemie und Biochemie, Technische Universität Darmstadt, Alarich-Weiss-Strasse 4, 64287, Darmstadt, Germany.
  • Reggelin M; Clemens-Schöpf-Institut für Organische Chemie und Biochemie, Technische Universität Darmstadt, Alarich-Weiss-Strasse 4, 64287, Darmstadt, Germany.
Chempluschem ; 84(2): 143, 2019 02.
Article in En | MEDLINE | ID: mdl-31950700
ABSTRACT
Invited for this month's cover are the collaborating groups of Dr. Philippe Lesot (DR CNRS) at Université Paris-Sud/Université Paris-Saclay, France, and Professor Michael Reggelin at TU Darmstadt, Germany. The cover shows the proton-decoupled natural abundance deuterium (NAD-{1 H}) Q-resolved Fz 2D-NMR spectrum of (±)-3-methylhexane measured in the anisotropic lyotropic chiral liquid-crystalline phase formed by a concentrated solution of a helically chiral polyarylacetylene in chloroform solvent. Seventeen out of the twenty possible deuterium quadrupolar doublets are observed, demonstrating the enormous enantiodifferentiating capability of the system, even for an unfunctionalized chiral alkane. Read the full text of the article at 10.1002/cplu.201800493.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Peptides / Polyacetylene Polymer Country/Region as subject: Europa Language: En Journal: Chempluschem Year: 2019 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Peptides / Polyacetylene Polymer Country/Region as subject: Europa Language: En Journal: Chempluschem Year: 2019 Document type: Article Affiliation country: