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Diazaphospholene-Catalyzed Hydrodefluorination of Polyfluoroarenes with Phenylsilane via Concerted Nucleophilic Aromatic Substitution.
Zhang, Jingjing; Zhao, Xiao; Yang, Jin-Dong; Cheng, Jin-Pei.
Affiliation
  • Zhang J; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 100084, China.
  • Zhao X; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 100084, China.
  • Yang JD; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 100084, China.
  • Cheng JP; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 100084, China.
J Org Chem ; 87(1): 294-300, 2022 01 07.
Article in En | MEDLINE | ID: mdl-34933552
ABSTRACT
The metal-free catalytic C-F bond activation of polyfluoroarenes was achieved with diazaphospholene as the catalyst and phenylsilane as the terminal reductant. Density functional theory calculations suggested a concerted nucleophilic aromatic substitution mechanism.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Metals Language: En Journal: J Org Chem Year: 2022 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Metals Language: En Journal: J Org Chem Year: 2022 Document type: Article Affiliation country: