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Non-innocent redox behavior of CuII-p-dimethylaminophenolate complexes: formation and characterization of the CuI-phenoxyl radical species.
Shima, Yuto; Suzuki, Takashi; Abe, Hitoshi; Yajima, Tatsuo; Mori, Seiji; Shimazaki, Yuichi.
Affiliation
  • Shima Y; Graduate School of Science and Engineering, Ibaraki University. Bunkyo, Mito 310-8512, Japan. yuichi.shimazaki.sci@vc.ibaraki.ac.jp.
  • Suzuki T; Graduate School of Science and Engineering, Ibaraki University. Bunkyo, Mito 310-8512, Japan. yuichi.shimazaki.sci@vc.ibaraki.ac.jp.
  • Abe H; Graduate School of Science and Engineering, Ibaraki University. Bunkyo, Mito 310-8512, Japan. yuichi.shimazaki.sci@vc.ibaraki.ac.jp.
  • Yajima T; Department of Materials Structure Science, School of High Energy Accelerator Science, SOKENDAI (the Graduate University for Advanced Studies), 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan.
  • Mori S; Institute of Materials Structure Science (IMSS), High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan.
  • Shimazaki Y; Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan.
Chem Commun (Camb) ; 58(44): 6401-6404, 2022 May 30.
Article in En | MEDLINE | ID: mdl-35543291
ABSTRACT
Cu complexes with p-dimethylaminophenolate ligands were synthesized by the reaction of CuII ions with the ligands under inert gas atmosphere and characterized. The complexes showed a valence state change from CuII-phenolate to CuI-phenoxyl radical on loss of the coordinated solvent. The CuI-phenoxyl radical species showed the characteristic properties and reactivities.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Phenols / Copper Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Phenols / Copper Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country: