Defect management by a cesium fluoride-modified electron transport layer promotes perovskite solar cells.
Phys Chem Chem Phys
; 24(37): 22562-22571, 2022 Sep 28.
Article
in En
| MEDLINE
| ID: mdl-36102344
ABSTRACT
SnO2 is a candidate material for electron transport layers (ETLs) in perovskite solar cells (PSCs). However, a large number of defects at the SnO2/perovskite interface lead to notable non-radiative interfacial recombination. Moreover, the energy level arrangement between SnO2/perovskite does not match well. In this study, a SnO2/CsF-SnO2 double-layer ETL was prepared by doping CsF into SnO2, effectively passivating the defects of the SnO2 ETL and SnO2/perovskite interface. The formation of a good energy level arrangement with the perovskite layer reduces the interface non-radiative recombination and improves the performance of the interface charge extraction. The photoelectric conversion efficiency of the optimal CsF-modified PSC reached 22.18%, owing to the significant increase in the open-circuit voltage to 1.180 V.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Phys Chem Chem Phys
Journal subject:
BIOFISICA
/
QUIMICA
Year:
2022
Document type:
Article