Light, Heat and Electricity Integrated Energy Conversion System: Photothermal-Assisted Co-Electrolysis of CO2 and Methanol.
Angew Chem Int Ed Engl
; 61(50): e202212162, 2022 Dec 12.
Article
in En
| MEDLINE
| ID: mdl-36229417
Strategy that can design powerful photothermal-catalysts to achieve photothermal-effect assisted coupling-catalysis is much desired for the improvement of energy conversion efficiency and redox product value in CO2 electroreduction system. Herein, a kind of bifunctional viologen-containing covalent organic framework (Ni-2CBpy2+ -COF) has been prepared and successfully applied in photothermal-assisted co-electrolysis of CO2 and methanol. Specifically, the FECO (cathode) and FEHCOOH (anode) for Ni-2CBpy2+ -COF can reach up to ≈100 % at 1.9â
V with ≈31.5 % saved overall electricity-consumption when the anodic oxygen evolution reaction (OER) is replaced by methanol oxidation. The superior performance could be attributed to the cyclic diquats in Ni-2CBpy2+ -COF that enhance the photothermal effect (ΔT=49.1 °C) to accelerate faster charge transfer between catalyst and immediate species as well as higher selectivity towards desired products as revealed by DFT calculations and characterizations.
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01-internacional
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MEDLINE
Language:
En
Journal:
Angew Chem Int Ed Engl
Year:
2022
Document type:
Article
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