Electrochemical Incorporation of Electrophiles into the Biomass-Derived Platform Molecule 5-(Chloromethyl)furfural.
ChemSusChem
; 16(5): e202201787, 2023 Mar 08.
Article
in En
| MEDLINE
| ID: mdl-36525531
ABSTRACT
The 5-(chloromethyl)furfural (CMF) derivative ethyl 5-(chloromethyl)furan-2-carboxylate undergoes two-electron electrochemical reduction in a simple, undivided cell to give the corresponding furylogous enolate anion, which can either be quenched with carbon dioxide to give a 5-(carboxymethyl)furan-2-carboxylate or with hydrogen ion to give a 5-methylfuran-2-carboxylate, thereby expanding the derivative scope of CMF as a biobased platform molecule.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ChemSusChem
Journal subject:
QUIMICA
/
TOXICOLOGIA
Year:
2023
Document type:
Article
Affiliation country: