A novel aminated lignin/geopolymer supported with Fe nanoparticles for removing Cr(VI) and naphthalene: Intermediates promoting the reduction of Cr(VI).

A novel, inexpensive and eco-friendly aminated lignin/geopolymer supported with Fe nanoparticles (Fe@N-L-GM) composite was successfully synthesized using kaolin and lignin as the major precursors. The prepared Fe@N-L-GM had larger specific surface area, rich oxygen-containing and nitrogen-containing functional groups, greater electron transfer ability and interconnective porous structure. The Fe@N-L-GM could be employed as the adsorbent of Cr(VI) and the activator of potassium peroxymonosulfate (PMS) for treatment of Cr(VI) and naphthalene (NAP) in wastewater. The adsorption and degradation results indicated that the maximum adsorption capacity of Cr(VI) could reach 65.83 mg g-1, whereas the maximum NAP degradation efficiency could reach 97.81 %. The adsorbed Cr(VI) was mostly converted to the low toxic Cr(III) through the reduction of electron donors such as Fe(II), amino and hydroxyl groups. The quenching experiment results confirmed that ·OH might be the crucial ROSs in mediating NAP degradation. In the simultaneous removal experiment of Cr(VI) and NAP, the Cr(VI) removal rate was significantly improved in the presence of NAP, while phenol as the degradation intermediate of NAP might be the main substance for promoting the reduction of Cr(VI). This work provided the theoretical foundation and a new type of material for the simultaneous removal of heavy metal and persistent organic pollutants (POPs).