Anionic Regulation toward Bi3+ Selective Occupation for Full-Spectrum White Light Emission.

ABSTRACT

An activator's selective occupation of a host is of great significance for designing high-quality white light-emitting diode phosphors, while achieving a full-spectrum single-phase white light emission phosphor is challenging. In this study, a boron phosphate solid-solution Na2Y2(BO3)2-x(PO4)xO0.005 Bi3+ (NYB2-xPxO0.005 Bi3+) white phosphor was designed by selectively occupying Bi3+ activators in the mixed anionic groups. The substitutes of the anionic unit (BO3)3- by the (PO4)3- unit are supposed to force part of the Bi3+ ion to enter the Na lattice site, which produces an intense orange-red emission peaked at 590 nm. In parallel, spectral tuning from blue to white light and an internal quantum efficiency of 56.42% was obtained, and the thermal stabile luminescence intensity remains at 94.2% of the initial intensity after four heating-cooling cycles from 30 to 210 °C (luminescent intensity is 83.6% of room temperature (RT) at 150 °C, with excellent thermal stability and recovery performance). Finally, an excellent color rendering index (Ra = 90.8 and R9 = 85) was demonstrated for white light-emitting diode devices using only an NYB1.5P0.5O0.005 Bi3+ phosphor and a near-ultraviolet (n-UV) 365 nm LED chip. This work delves into the different selective occupancy of Bi3+ ions and explores a new avenue for the design of phosphors for full-spectrum white light emission.