2D Covalent Organic Frameworks with Kagome Lattice: Synthesis and Applications.

ABSTRACT

2D covalent organic frameworks with Kagome (kgm) topology are a promising class of crystalline frameworks that possess both triangular and hexagonal pores. These dual-pore structures enable kgm COFs to exhibit unique advantages in selective separation, mass transfer, and targeted drug release. However, the synthesis of 2D kgm COFs has been hindered by the reliance on empirical methods. This review systematically summarizes the conventional macrocycle-to-framework strategy, typical [4+2] co-polymerization synthetic strategy, and bifunctional molecules self-condensation approach for constructing 2D kgm COFs. Factors influencing the formation of kgm lattice are surveyed, such as monomer type, solvent polarity, substrate concentration, etc., and highlight the representative examples on targeted synthesis. Additionally, applications of 2D kgm COFs and relationships between structure and performances are summarized. Finally, key fundamental perspectives are proposed to accelerate the further development of this intriguing material.