Selective detection of ionic liquid fluorescence probes for visual colorimetry of different metal ions.

ABSTRACT

At present, the fast distinction of different metal ions in pure water media is not only a great challenge, but also drives the protection of water quality in environmental water bodies. In this paper, a novel ionic liquid fluorescent probe Glycolic Acid-L-Arginine (GA-L-Arg) was rationally created and designed through an in-depth study of ionic liquids. It is also used as an innovative multi-ion fluorescent probe for colorimetric detection and separate identification of Fe3+ and Co2+ in aqueous solutions of various metal ions. GA-L-Arg has excellent water solubility due to the strong hydrophilicity of Glycolic Acid and L-Arginine. The probe showed high sensitivity, extremely significant selectivity, and great pH stability for Fe3+ and Co2+ in pure water. The GA-L-Arg structure and the mechanism of Fe3+ and Co2+ detection were analyzed by infrared spectroscopic characterization and quantum chemical calculations. More importantly, the distinct colorimetric partitioning of Fe3+ and Co2+ was performed by the unique extraction of Fe3+ in the presence of the fluorescent probe and buffer solution.