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Concave P-Stereogenic Phosphorodiamidite Ligands for Enantioselective Rh(I) Catalysis.
Saleh, Nidal; Besnard, Céline; Lacour, Jérôme.
Affiliation
  • Saleh N; Department of Organic Chemistry, University of Geneva, 1211 Geneva 4, Switzerland.
  • Besnard C; Laboratory of Crystallography, University of Geneva, 1211 Geneva 4, Switzerland.
  • Lacour J; Department of Organic Chemistry, University of Geneva, 1211 Geneva 4, Switzerland.
Org Lett ; 26(11): 2202-2206, 2024 Mar 22.
Article in En | MEDLINE | ID: mdl-38471122
ABSTRACT
The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger's bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (er up to 928).
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2024 Document type: Article Affiliation country:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2024 Document type: Article Affiliation country: