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A fluorinated metal-organic framework-based quasi-solid electrolyte for stabilizing Li metal anodes.
Wang, Xiang; Bai, Mengxi; Li, Qiufen; Li, Jiashuai; Li, Dongze; Lin, Xiaoyan; Shao, Siyuan; Wang, Ziqi.
Affiliation
  • Wang X; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Bai M; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Li Q; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Li J; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Li D; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Lin X; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Shao S; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
  • Wang Z; Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China. wangzq@jnu.edu.cn.
Chem Commun (Camb) ; 60(62): 8067-8070, 2024 Jul 30.
Article in En | MEDLINE | ID: mdl-38989664
ABSTRACT
A fluorinated quasi-solid electrolyte (QSE) with a high conductivity of 2.3 mS cm-1 is meticulously designed for Li metal batteries. It facilitates the formation of a LiF-rich solid electrolyte interface that effectively enhances the reversibility of Li anodes. The assembled Li|QSE|LiFePO4 batteries exhibit 92.3% capacity retention after 1500 cycles and an impressive capacity of up to 45 mA h g-1 at 20C.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: