Vibrational spectroscopy of dynamic interactions and relaxation processes in ionic systems.

ABSTRACT

In recent years, there has been a boom in the publication of research results on ionic (electrolyte) systems used in the creation of electrochemical energy systems (batteries, supercapacitors, etc.). One of the alternative ways to obtain dynamic information in ionic systems is spectroscopic experiments, and the most valuable information on the behavior of condensed systems at picosecond and adjacent time intervals is provided by vibrational spectroscopy. The source of this information is the analysis of the shape and width of the lines in the vibrational spectra of ion systems. This review aims to systematize the theoretical and methodological aspects of the study of the dynamics of ion systems by vibrational spectroscopy.